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The search for high cycle life, high capacity, self healing negative electrodes for lithium ion batteries and a potential solution based on lithiated gallium

Published online by Cambridge University Press:  07 July 2011

Mark W. Verbrugge ,
Rutooj D. Deshpande ,
Juchuan Li  and
Yang-Tse Cheng
Mark W. Verbrugge
Affiliation:
Chemical Sciences and Materials Systems Laboratory, General Motors Research and Development Center, Warren, MI 48090, USA
Rutooj D. Deshpande
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky 40506, USA
Juchuan Li
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky 40506, USA
Yang-Tse Cheng
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky 40506, USA
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Abstract

Automotive components, for the most part, are designed to last for the life of the vehicle. This is especially true for more expensive subsystems. As we move towards electrified vehicles with large traction batteries, it becomes increasingly important to (a) reduce the cost of the batteries and (b) improve battery life. This life challenge for the traction battery is quite different from that of most consumer electronics applications, which often require no more than a few years of life and a few hundred cycles of full charge and discharge. In this paper, we provide context for the automotive battery landscape and subsequently introduce a potential solution pathway to the cycle life problem associated with high capacity negative electrodes for lithium ion batteries. The approach is based on a solid (in the substantially lithiated state) to liquid (in the absence of significant lithium) transition for the gallium electrode. Because of gallium’s low melting point (29°C), heating the cell to just above ambient temperature transforms the electrode to a semi-liquid state, cracks vanish, to a large extent, and the electrode heals.

Keywords

energy storageGaLi
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1333: Symposium M – Nanostructured Materials for Energy Storage , 2011 , mrss11-1333-m05-04
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1. Chalk, S.G. and Miller, J.E., Key challenges and recent progress in batteries, fuel cells, and hydrogen storage for clean energy systems. J. Power Sources, 159(1): 73–80 (2006).Google Scholar
2. Fletcher, S., Power Struggle. Popular Science, (Nov): 50-107(2008).Google Scholar
3. Armand, M. and Tarascon, J.M., Building Better Batteries. Nature, 451 (7179): 652-657(2008).Google Scholar
4. Interim Joint Technical Assessment Report:Light-Duty Vehicle Greenhouse Gas Emission Standards and Corporate Average Fuel Economy Standards for Model Years 2017-2025. Office of Transportation and Air Quality, U.S. Environmental Protection Agency;Office of International Policy, Fuel Economy, and Consumer Programs, National Highway Traffic Safety Administration; U.S. Department of Transportation;California Air Resources Board; California Environmental Protection Agency (2010).Google Scholar
5. Verbrugge, M.W. and Cheng, Y.T., Stress and Strain-Energy Distributions within Diffusion-Controlled Insertion-Electrode Particles Subjected to Periodic Potential Excitations, J. Electrochem. Soc., 156(11): A927–A937 (2009).Google Scholar
6. Deshpande, R., Cheng, Y.T., and Verbrugge, M.W., Modeling diffusion-induced stress in nanowire electrode structures. J. Power Sources, 195(15): 5081–5088 (2010).Google Scholar
7. Cheng, Y.T. and Verbrugge, M.W., The influence of surface mechanics on diffusion induced stresses within spherical nanoparticles. J. Appl. Phys., 104(8) (2008).Google Scholar
8. Verbrugge, M.W. and Cheng, Y.-T. How Long do Lithium Ion Cells Last? in Proceedings Volume for the 26th International Battery Seminar & Exhibit. Fort Lauderdale, Florida (2009).Google Scholar
9. Larcher, D., Beattie, S., Morcrette, M., Edstroem, K., Jumas, J.C., and Tarascon, J.M., Recent Findings and Prospects in the Field of Pure Metals as Negative Electrodes for Li-Ion Batteries. J. Mater. Chem., 17(36): 3759–3772 (2007).Google Scholar
10. Huggins, R.A., Advanced Batteries: Materials Science Aspects. 2009: Springer.Google Scholar
11. Xia, Y.Y., Sakai, T., Fujieda, T., Wada, M., and Yoshinaga, H., Flake Cu-Sn alloys as Negative Electrode Materials for Rechargeable Lithium Batteries. J. Electrochem. Soc., 148(5): A471–A481 (2001).Google Scholar
12. Todd, A.D.W., Mar, R.E., and Dahn, J.R., Tin-Transition Metal-Carbon Systems for Lithium-Ion Battery Negative Electrodes. J. Electrochem. Soc., 154(6): A597–A604 (2007).Google Scholar
13. Hassoun, J., Panero, S., and Scrosati, B., Electrodeposited Ni-Sn Intermetallic Electrodes for Advanced Lithium Ion Batteries. J. Power Sources, 160(2): 1336–1341 (2006).Google Scholar
14. Graetz, J., Ahn, C.C., Yazami, R., and Fultz, B., Highly Reversible Lithium Storage in Nanostructured Silicon. Electrochem. Solid State Lett., 6(9): A194–A197 (2003).Google Scholar
15. Kim, H., Seo, M., Park, M.H., and Cho, J., A Critical Size of Silicon Nano-Anodes for Lithium Rechargeable Batteries. Angew. Chem.-Int. Edit., 49(12): 2146–2149 (2010).Google Scholar
16. Chan, C.K., Peng, H.L., Liu, G., McIlwrath, K., Zhang, X.F., Huggins, R.A., and Cui, Y., High-Performance Lithium Battery Anodes using Silicon Nanowires. Nat. Nanotechnol., 3(1): 31–35 (2008).Google Scholar
17. Armstrong, G., Armstrong, A.R., Bruce, P.G., Reale, P., and Scrosati, B., TiO2(B) Nanowires as An Improved Anode Material for Lithium-Ion Batteries Containing LiFePO4 or LiNi0.5Mn1.5O4 Cathodes and A Polymer Electrolyte. Adv. Mater., 18(19): 2597–2600 (2006).Google Scholar
18. Shin, H.C., Dong, J., and Liu, M.L., Porous Tin Oxides Prepared using an Anodic Oxidation Process. Adv. Mater., 16(3): 237–240 (2004).Google Scholar
19. Bao, S.J., Bao, Q.L., Li, C.M., and Dong, Z.L., Novel Porous Anatase TiO2 Nanorods and their High Lithium Electroactivity. Electrochem. Commun., 9(5): 1233–1238 (2007).Google Scholar
20. Winter, M., The Solid Electrolyte Interphase - The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries. Z. Phys. Chemie-Int. J. Res. Phys. Chem. Chem. Phys., 223(10-11): 1395–1406 (2009).Google Scholar
21. Wen, C.J. and Huggins, R.A., Electrochemical Investigation of the Lithium-Gallium System. J. Electrochem. Soc., 128(8): 1636–1641 (1981).Google Scholar
22. Saint, J., Morcrette, M., Larcher, D., and Tarascon, J.M., Exploring the Li-Ga Room Temperature Phase Diagram and the Electrochemical Performances of the LixGay Alloys vs. Li. Solid State Ion., 176(1-2): 189–197 (2005).Google Scholar
23. Lee, K.T., Jung, Y.S., Kwon, J.Y., Kim, J.H., and Oh, S.M., Role of Electrochemically Driven Cu Nanograins in CuGa2 Electrode. Chem. Mat., 20(2): 447–453 (2008).Google Scholar
24. Lee, K.T., Jung, Y.S., Kim, T., Kim, C.H., Kim, J.H., Kwon, J.Y., and Oh, S.M., Liquid Gallium Electrode Confined in Porous Carbon Matrix as Anode for Lithium Secondary Batteries. Electrochem. Solid State Lett., 11(3): A21–A24 (2008).Google Scholar
25. Predel, B., Group IV Physical Chemistry - Phase Equilibria, Crystallographic and Thermodynamic Data of Binary Alloys. Electronic Materials and Semiconductors, ed. , M.O. Vol. 5. 1998: Springer.Google Scholar
26. Verbrugge, M.W. and Koch, B.J., Electrochemical analysis of lithiated graphite anodes. J. Electrochem. Soc., 150(3): A374–A384 (2003).Google Scholar