Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-25T15:42:04.120Z Has data issue: false hasContentIssue false
  • English
  • Français

SANS Studies of the Configurations of Single Chains in Heterogeneous Block Copolymers

Published online by Cambridge University Press:  26 February 2011

C. V. Berney ,
P. Cheng ,
P. Kofinas  and
R. E. Cohen
C. V. Berney
Affiliation:
Massachusetts Institute of Technology Cambridge, MA 02139
P. Cheng
Affiliation:
Massachusetts Institute of Technology Cambridge, MA 02139
P. Kofinas
Affiliation:
Massachusetts Institute of Technology Cambridge, MA 02139
R. E. Cohen
Affiliation:
Massachusetts Institute of Technology Cambridge, MA 02139
Get access

Abstract

Small-angle neutron scattering studies of polystyrene-polybutadiene diblock copolymers of spherical morphology are discussed, with emphasis on the effect of this morphology on the spatial organization of the polymer chains. Three particular cases are examined: (i) the distribution within the matrix of added (matrix) homopolymer, (ii) the distribution within the spherical microdomains of added (microdomain) homopolymer, and (iii) isotopic effects occurring in the B domains when a B-deuterated diblock SBd is blended with a normal sample SB. Deviations from ideal mixing are found in all three cases.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 79: Symposium F – Scattering, Deformation and Fracture in Polymers , 1986 , 175
Copyright
Copyright © Materials Research Society 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Noshay, A. and McGrath, J.E., “Block Copolymers, Overview and Critical Survey”, Academic Press, NY 1977.Google Scholar
2. “Developments in Block Copolymers-l”, edited by Goodman, I., Applied Science Publishers, London, 1982.Google Scholar
3. Manson, J.A. and Sperling, L.H., “Polymer Blends and Composites”, Plenum Press, New York, 1976.Google Scholar
4. Richards, R.W., Adv. Polymer Sci., 71, 1(1985).Google Scholar
5. Bates, F.S., Cohen, R.E. and Berney, C.V., Macromolecules, 15, 589 (1982).CrossRefGoogle Scholar
6. Bates, F.S., Berney, C.V. and Cohen, R.E., Macromolecules, 16, 1101 (1983).CrossRefGoogle Scholar
7. Berney, C.V., Cohen, R.E., and Bates, F.S., Polymer, 23, 1222 (1982).Google Scholar
8. Jahshan, S.N. and Summerfield, G.C., J. Polymer Sci., Phys., 18, 1859 (1980).Google Scholar
9. Koberstein, J.T., J. Polymer Sci., Phys., 20, 593 (1982).Google Scholar
10. Bates, F.S., Berney, C.V., Cohen, R.E. and Wignall, G.D., Polymer, 24, 519 (1983).CrossRefGoogle Scholar
11. Gennes, P-G. de, “Scaling Concepts in Polymer Physics” Cornell University Press, Ithaca 1979.Google Scholar
12. Bates, F.S., Cohen, R.E. and Argon, A.S., Macromolecules, 16, 1108 (1983).Google Scholar
13. Berney, C.V., Cheng, P. and Cohen, R.E., to be submitted.Google Scholar
14. Debye, P., Phys. Colloid Chem., 51, 18 (1947).CrossRefGoogle Scholar
15. Percus, J.K. and Yevick, G.J., Phys. Rev., 110, 1 (1958).Google Scholar
16. Kinning, D.J. and Thomas, E.L., Macromolecules, 17, 1712 (1984).Google Scholar
17. Leibler, L. and Pincus, P.A., Macromolecules, 17, 2922 (1984).Google Scholar
18. Whitmore, M.D. and Noolandi, J., Macromolecules, 18, 657 (1985).Google Scholar
19. Bates, F.S., Wignall, G.D. and Koehler, W.C., Phys. Rev. Letters, 55, 2425 (1985).Google Scholar