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Room Temperature Current Suppression on Magnetic Tunnel Junction Based Molecular Spintronics Devices

Published online by Cambridge University Press:  09 August 2013

Pawan Tyagi*
Affiliation:
Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky-40506, USA
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Abstract

Molecular conduction channels between two ferromagnetic electrodes can produce strong exchange coupling and dramatic effect on the spin transport, thus enabling the realization of novel logic and memory devices. To realize such device, we produced Multilayer Edge Molecular Spintronics Devices (MEMSDs) by bridging the organometallic molecular clusters (OMCs) across a ∼2 nm thick insulator of a magnetic tunnel junction (MTJ), along its exposed side edges. These MEMSDs exhibited unprecedented increase in exchange coupling between ferromagnetic films and dramatic changes in the spin transport. This paper focuses on the dramatic current suppression phenomenon exhibited by MEMSDs at room temperature. In the event of current suppression, the effective MEMESDs’ current reduced by as much as six orders in magnitude as compared to the leakage current level of a MTJ test bed. Current suppression phenomenon was found to be associated with the equally dramatic changes in the MTJ test beds due to OMCs. Role of OMC in changing MTJ test bed properties was determined by the three different types of magnetic characterizations: SQUID Magnetometer, Ferromagnetic Resonance, and Magnetic Force Microscopy. Observation of current suppression by independent research groups and supporting studies on similar systems will be crucially important to unequivocally establish the utility of MEMSD approach.

Type
Articles
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Rocha, A. R., Garcia-Suarez, V. M., Bailey, S. W., Lambert, C. J., Ferrer, J., and Sanvito, S., “Towards molecular spintronics,” Nat. Mater., vol. 4, pp. 335339, Apr 2005.CrossRefGoogle ScholarPubMed
Lehmann, J., Gaita-Arino, A., Coronado, E., and Loss, D., “Quantum computing with molecular spin systems,” J. Mater. Chem., vol. 19, pp. 16721677, 2009.CrossRefGoogle Scholar
Coronado, E. and Epsetin, A. J., “Molecular spintronics and quantum computing,” J. Mater. Chem., vol. 19, pp. 16701671, 2009.Google Scholar
Petrov, E. G., Tolokh, I. S., Demidenko, A. A., and Gorbach, V. V., “Electron-Transfer Properties of Quantum Molecular Wires,” Chem. Phys., vol. 193, pp. 237253, Apr 15 1995.CrossRefGoogle Scholar
Petrov, E. G., Tolokh, I. S., and May, V., “Magnetic field control of an electron tunnel current through a molecular wire,” J. Chem. Phys., vol. 108, pp. 43864396, Mar 15 1998.CrossRefGoogle Scholar
Leuenberger, M. N. and Mucciolo, E. R., “Berry-phase oscillations of the kondo effect in single-molecule magnets,” Phys. Rev. Lett., vol. 97, p. 126601, Sep 22 2006.CrossRefGoogle ScholarPubMed
Martinek, J., Sindel, M., Borda, L., Barnas, J., Konig, J., Schon, G., et al. ., “Kondo effect in the presence of itinerant-electron ferromagnetism studied with the numerical renormalization group method,” Phys. Rev. Lett., vol. 91, p. 247202, Dec 12 2003.CrossRefGoogle ScholarPubMed
Martinek, J., Utsumi, Y., Imamura, H., Barnas, J., Maekawa, S., Konig, J., et al. ., “Kondo effect in quantum dots coupled to ferromagnetic leads,” Phys. Rev. Lett., vol. 91, Sep 19 2003.CrossRefGoogle ScholarPubMed
Pasupathy, A. N., Bialczak, R. C., Martinek, J., Grose, J. E., Donev, L. A. K., McEuen, P. L., et al. ., “The Kondo effect in the presence of ferromagnetism,” Science, vol. 306, pp. 8689, Oct 1 2004.CrossRefGoogle ScholarPubMed
Tyagi, P., “Molecular Spin Devices: Current Understanding and New Territories,” Nano, vol. 4, pp. 325338 2009.CrossRefGoogle Scholar
Tyagi, P., Li, D. F., Holmes, S. M., and Hinds, B. J., “Molecular electrodes at the exposed edge of metal/insulator/metal trilayer structures,” J. Am. Chem. Soc., vol. 129, pp. 49294938, Apr 25 2007.CrossRefGoogle ScholarPubMed
Tyagi, P., “Multilayer edge molecular electronics devices,” J. Mater. Chem., vol. 21, pp. 47334742, 2011.CrossRefGoogle Scholar
Tyagi, P., “PhD Thesis: Fabrication and Characterization of Molecular Spintronics Devices,” University of Kentucky (http://archive.uky.edu/handle/10225/878), Ph.D2008.Google Scholar
Tyagi, P., “Multilayer edge molecular electronics devices: a review,” J. Mater. Chem., vol. 21, pp. 47334742, 2011.CrossRefGoogle Scholar
Tyagi, P., “Molecular electrodes at the exposed edge of metal/insulator/metal trilayer structures,” J. Nanoparticle Res., vol. 14, p. 1195, 2012.CrossRefGoogle Scholar
Tyagi, P. and Hinds, B. J., “Mechanism of Ultrathin Tunnel Barrier Failure Due to Mechanical Stress Induced Nano-Sized Hillocks and Voids,” J. Vac. Sci. Technol. B, vol. 28, pp. 517521, 2010.CrossRefGoogle Scholar
Tyagi, P., “Room temeperature current suppression on multilayer edge molecular spintronics device,” arXiv:1111.6352v1 [cond-mat.mes-hall], p., 2011.Google Scholar
Tyagi, P., “Photovoltaic Effect on Molecule Coupled Ferromagnetic Films of a Magnetic Tunnel Junction,” arXiv:1112.1879v1 [cond-mat.mes-hall], p., 2011.Google Scholar
Tyagi, P., “Molecule induced strong exchange coupling between ferromagnetic electrodes of a magnetic tunnel junction,” arXiv:1110.0885v1 [cond-mat.mtrl-sci], p., 2011.Google Scholar
Demokritov, S. O., “Biquadratic interlayer coupling in layered magnetic systems,” J. Phys. D-Appl. Phys., vol. 31, pp. 925941, Apr 21 1998.CrossRefGoogle Scholar
Gareev, R. R., Pohimann, L. L., Stein, S., Burgler, D. E., Grunberg, P. A., and Siegel, M., “Tunneling in epitaxial Fe/Si/Fe structures with strong antiferromagnetic interlayer coupling,” J. Appl. Phys., vol. 93, p. 8038, May 15 2003.CrossRefGoogle Scholar
Baberschke, K., “Magnetic anisotropy energy and interlayer exchange coupling in ultrathin ferromagnets: Experiment versus theory,” Phil. Mag., vol. 88, pp. 26432654, 2008.CrossRefGoogle Scholar
Layadi, A., “Ferromagnetic resonance modes in coupled layers with cubic magnetocrystalline anisotropy,” J. App. Phys., vol. 83, pp. 37383743, Apr 1 1998.CrossRefGoogle Scholar
D'Angelo, C. and Tyagi, P., “Molecular Magnet Induced Transformative Effects in Molecular Spintronics Devices: A Monte Carlo Study,” presented at the 2012 MRS Fall Meeting, Boston, MA, 2013.CrossRefGoogle Scholar