Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-29T07:38:30.329Z Has data issue: false hasContentIssue false

The Role of H in the Growth Mechanism of PECVD a-Si:H

Published online by Cambridge University Press:  15 February 2011

M.C.M. Van de Sanden
Affiliation:
Eindhoven University of Technology, Department of Applied Physics, P.O.Box 513, 5600 MB, Eindhoven, Netherlands, [email protected]
W.M.M. Kessels
Affiliation:
Eindhoven University of Technology, Department of Applied Physics, P.O.Box 513, 5600 MB, Eindhoven, Netherlands
A.H.M. Smets
Affiliation:
Eindhoven University of Technology, Department of Applied Physics, P.O.Box 513, 5600 MB, Eindhoven, Netherlands
B.A. Korevaar
Affiliation:
Eindhoven University of Technology, Department of Applied Physics, P.O.Box 513, 5600 MB, Eindhoven, Netherlands
R.J. Severens
Affiliation:
AKZO-NOBEL Central Research, P.O.Box 9300, 6800 SB, Arnhem, Netherlands
D.C. Schram
Affiliation:
Eindhoven University of Technology, Department of Applied Physics, P.O.Box 513, 5600 MB, Eindhoven, Netherlands
Get access

Abstract

This paper describes an extension of the silyl radical based kinetic growth model by atomic hydrogen induced surface hydrogen abstraction processes. It is shown that by including this direct abstraction process several problems of the SiH 3 based model are resolved. The defect density can be predicted with the proper temperature dependence and order of magnitude. The implications for high rate deposition of a-Si:H are discussed

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Matsuda, A., Nomoto, K., Takeuchi, Y., Suzuki, A., Yuuki, A., Perrin, J., Surf. Sci. 22, 50 (1990), A. Matsuda, T. Goto, Mat. Res. Soc. Symp. Proc. 164, 3 (1990), J.L. Guizot, K. Nomoto, A. Matsuda, Surf. Sci. 244, 22 (1991)Google Scholar
[2] Doyle, J.R., Doughty, D.A., Gallagher, A., J. Appl. Phys. 68, 4375 (1990), J.R. Doyle, D.A. Doughty, A. Gallagher, J. Appl. Phys. 71, 4727 (1992), J.R. Doyle, D.A. Doughty, A. Gallagher, J. Appl. Phys. 71, 4771 (1992)Google Scholar
[3] Perrin, J., Takeda, Y., Hitano, N., Takeuchi, Y., Matsuda, A., Surf. Sci. 210, 114 (1989), J. Perrin, M. Shiritani, P. Kae-Nune, H. Videlot, J. Jolly, J. Guillon, J. Vac. Sci. Technol. A 16, 278 (1998)Google Scholar
[4] Miyazaki, K., Mishiro, Y., Kajiwara, T., Uchino, K., Muraoka, K., Okada, T., Maeda, M., J. Vac. Sci. Technol. A 17, 155 (1999)Google Scholar
[5] Sanden, M.C.M. van de, Severens, R.J., Kessels, W.M.M., Pas, F. van de, IJzendoorn, L.J. van, Schram, D.C., Mat. Res. Soc. Symp. Proc. 467, 621 (1997), M.C.M. van de Sanden, R.J. Severens, W.M.M. Kessels, D.C. Schram, Plasma Phys. Control. Fusion 41, A365 (1999)Google Scholar
[6] Robertson, J., Powell, M.J., Mat. Res. Soc. Symp. Proc. 507, 897 (1998)Google Scholar
[7] see e.g. Sinniah, K., Sherman, M.G., Lewis, L.B., Weinberg, W.H., Yates, J.T. and Janda, K.C., Phys. Rev. Lett. 62, 567 (1989)Google Scholar
[8] Toyoshima, Y., Arai, K., Matsuda, A., Tanaka, K., J. Appl. Phys. 56, 1540 (1990)Google Scholar
[9] Keudell, A. von, Abelson, J.R., Phys. Rev. B 59, 5791 (1999)Google Scholar
[10] Ramalingam, S., Maroudas, D., Aydill, E., Mat. Res. Soc. Symp. Proc. 507, 673 (1998)Google Scholar
[11] Kessels, W.M.M., Sanden, M.C.M. van de, Severens, R.J., IJzendoorn, L.J. van, Schram, D.C., Mat. Res. Soc. Symp. Proc. 507, 529 (1998)Google Scholar
[12] Kessels, W.M.M., Smets, A.H.M., Korevaar, B.A., Adriaenssens, G.J., Sanden, M.C.M. van de, Schram, D.C., these ProceedingsGoogle Scholar
[13] see e.g. Koleske, D.D., Gates, S.M., Jackson, B., J. Chem. Phys. 101, 3301 (1994)Google Scholar
[14] Widdra, W., Yi, S.I., Maboudian, R., Briggs, G.A.D., Weinberg, W.H., Phys. Rev. Lett. 74, 2074 (1995)Google Scholar
[15] Kessels, W.M.M., Severens, R.J., Sanden, M.C.M. van de, Schram, D.C., J. Non-Cryst. Solids 227–230, 133 (1998)Google Scholar
[16] Ganguly, G., Matsuda, A., Phys Rev. B 47, 3661 (1993) 18 Google Scholar