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Published online by Cambridge University Press: 09 August 2012
Emerging phase-change electrical memory technologies rely on the fast amorphous to crystalline transition, which is usually characterized by an ‘S-shape’ current-voltage curve. We investigate the possibility that electric field induced nucleation may play a dominant role in defining this characteristic electrical switching behavior. We derive quantitative crystallization maps to study the kinetics of the amorphous to crystalline transition in the presence of electric field contribution to the free energy and we investigate how the prediction of the electric field induced nucleation model is affected by material properties such as enthalpy and relative electric permittivity.