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Reduction of bis(Oxalato)Borate on a High Surface Area Carbon Electrode
Published online by Cambridge University Press: 15 March 2011
Abstract
Lithium bis(oxalato)borate (LiBOB) has gained widespread interest as an electrolyte salt for lithium ion batteries because of its high conductivity, low cost, thermal stability, and adequate solubility in many organic solvents [1]. Cyclic voltammetric data taken on platinum [2] and carbon [3] indicate electrochemical stability over a wide potential range.
We show that bis(oxalato)borate (BOB) can be reduced at about 1.75 volts anodic to lithium, by discharging electrolytes at low current density (0.1 mA/cm2) on high surface area carbon electrodes containing a mixture of acetylene and Ketjen carbon blacks. The evidence includes discharge profiles and 11B NMR data. The behavior of discharge plateaus indicates that BOB is reduced to a soluble species with electrolytic properties, and the appearance of a broad 11B NMR peak in the electrolyte indicates that the reduced species undergoes extensive exchange.
- Type
- Research Article
- Information
- MRS Online Proceedings Library (OPL) , Volume 1127: Symposium T – Mobile Energy , 2008 , 1127-T03-11
- Copyright
- Copyright © Materials Research Society 2009