Hostname: page-component-78c5997874-xbtfd Total loading time: 0 Render date: 2024-11-05T10:16:39.897Z Has data issue: false hasContentIssue false
  • English
  • Français

Reactive Poly(Arylene Ether) Toughening of Cyanate Ester Networks Via Thermal and MicrowaveCuring

Published online by Cambridge University Press:  15 February 2011

S. A. Srinivasan ,
S. S. Joardar ,
D. B. Priddy ,
T. C Ward  and
J. E. Mcgrath
S. A. Srinivasan
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and National Science Foundation Science and Technology Center: High Performance Polymeric Adhesives and Composites, Blacksburg, VA, 24061–0344
S. S. Joardar
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and National Science Foundation Science and Technology Center: High Performance Polymeric Adhesives and Composites, Blacksburg, VA, 24061–0344
D. B. Priddy
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and National Science Foundation Science and Technology Center: High Performance Polymeric Adhesives and Composites, Blacksburg, VA, 24061–0344
T. C Ward
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and National Science Foundation Science and Technology Center: High Performance Polymeric Adhesives and Composites, Blacksburg, VA, 24061–0344
J. E. Mcgrath
Affiliation:
Virginia Polytechnic Institute and State University, Department of Chemistry and National Science Foundation Science and Technology Center: High Performance Polymeric Adhesives and Composites, Blacksburg, VA, 24061–0344
Get access

Extract

Cyanate ester networks are receiving considerable attention as potential candidates for high temperature adhesives and composite applications. The dicyanates ester monomers cyclo-trimerize1,2 via addition polymerization to form highly crosslinked polycyanurates (Scheme 1).

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 347: Symposium O – Microwave Processing of Materials IV , 1994 , 705
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Shimp, D. A., Christenson, J. R. and Ising, S. J., ‘Arocy Cyanate Ester Resins: Chemistry and Properties’, Rhone-Poulenc, Inc. publication, (1989).Google Scholar
2. Gupta, A. M. and Macosko, C.W., Macromolecules, 26, 2455, (1993).Google Scholar
3. Arnold, C., Mackenzie, P., Malhotra, V., Pearson, D., Chow, N., Hearn, M. and Robinson, G., 37th Int′I SAMPE Symp., March 9–12, pg. 128, (1992).Google Scholar
4. Cao, Z. Q., Mechin, F., Pascault, J. P., Polym. Mat. Sci. Eng. Prepr. (PMSE), 70, 91, (1994).Google Scholar
5. Almen, G. R., SAMPE Int′l Tech. Conf., 21, 304, (1989).Google Scholar
6. Shimp, D. A., Hudock, F. A., Bobo, W. S., 18th Int′l SAMPE Tech. Conf., Oct. 7–9, pg. 851, 1986.Google Scholar
7. Hedrick, J. C., Viehbeck, A., Gotro, J. T., ACS Polym. Prepr., Polym. Chem, 35(1), 537, 1994.Google Scholar
8. Srinivasan, S. A. and McGrath, J. E., High Performance Polymers, Vol 5, p 259–274, 1993.Google Scholar
9. Srinivasan, S. A. and McGrath, J. E., SAMPE Quarterly, April, pgs. 25–29, (1993).Google Scholar
10. Liptak, S. C., Wilkinson, S. P., Hedrick, J. E., Ward, T. C. and McGrath, J. E., Radiation Effects on Polymers, ACS Symp. Ser. 475, 364 (1991).Google Scholar
11. Hedrick, J. C., Lewis, D. A., Lyle, G. D., Wu, S. D., Ward, T. C. and J. E.McGrath Polym. Mater. Sci. and Eng. Prepr., 60, 438, (1987).Google Scholar
12. Lewis, D. A., Hedrick, J. C., Lyle, G. D., Ward, T. C. and McGrath, J. E. in Microwave Processing of Materials, Sutton, W. H., Brooks, M. H., Chabinsky, I.I., eds., MRS Symp. Proc, Publishers Choice Book Manuf. Co., Mars, PA, 1988, Vol. 124, pp 181–188.Google Scholar
13. Metaxas, A. C., Meredith, R. J., Industrial Microwave Heating, Peter Peregrinus Ltd., London, (1983).Google Scholar
14. Ward, T. C., Chen, M, Siochi, E. J., McGrath, J. E., Polym. Eng. and Sci., 33, 1092, (1993);Google Scholar
Ward, T. C., Chen, M, Siochi, E. J., McGrath, J. E., Polym. Eng. and Sci., 33, 1110, (1993);Google Scholar
Ward, T. C., Chen, M, Siochi, E. J., McGrath, J. E., Polym. Eng. and Sci., 33, 33, 1122, (1993).Google Scholar
15. Viswanathan, R., Johnson, B. C. and McGrath, J. E., Polymer, 25, 1827, 1984.Google Scholar
16. Jurek, M. J. and McGrath, J. E., Polymer, 30, 1552, 1989;Google Scholar
Lyle, G. D., Senger, J. S., Chen, D. H., Kilic, S., Wu, S. D., Mohanty, D. K. and McGrath, J. E., Polymer, 30, 978 (1989).Google Scholar
17. Srinivasan, S. A., Joardar, S. S., Priddy, D. B. Jr, Ward, T. C. and McGrath, J. E., Polym. Mat Sci. Eng. Prepr. (PMSE), 70, 93, 1994.Google Scholar