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Raman Studies of Znse Lattice Damage and Recovery Due to N Implantation and Annealing

Published online by Cambridge University Press:  26 February 2011

A. Deneuville
Affiliation:
University of Florida, Gainesville, FL 32611.
P. Ayyub
Affiliation:
University of Florida, Gainesville, FL 32611.
C. H. Park
Affiliation:
University of Florida, Gainesville, FL 32611.
T. Anderson
Affiliation:
University of Florida, Gainesville, FL 32611.
P. Lowen
Affiliation:
University of Florida, Gainesville, FL 32611.
K.S. Jones
Affiliation:
University of Florida, Gainesville, FL 32611.
P. H. Holloway
Affiliation:
University of Florida, Gainesville, FL 32611.
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Abstract

The “bulk” and near-surface regions of N implanted heteroepitaxial ZnSe films were studied using the full width at half maximum (FWHM) of the LO phonon Raman line. The “bulk” FWHM has a minimum below an annealing temperature Ta = 400°C, and increases for higher Ta. This is attributed to the relaxation of residual stress, and to an increased stress from the formation of Zn vacancies. The surface FWHM has a deep minimum near Ta = 500°C which is attributed to the relaxation of the implantation damage at lower Ta, and stress induced by Zn vacancy formation at higher Ta. Another wider peak is found just after implantation and for Ta = 600°C, and results from a sum of two peaks attributed to the heavily damaged region around Rp and to the region with Zn vacancies.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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