Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-23T11:55:49.480Z Has data issue: false hasContentIssue false
  • English
  • Français

Quantitative Structure Analysis of Nano-sized Materials by Transmission Electron Microscopy

Published online by Cambridge University Press:  31 January 2011

Wolfgang Neumann ,
Holm Kirmse ,
Ines Häeusler ,
Changlin Zheng  and
Anna Mogilatenko
Wolfgang Neumann
Affiliation:
[email protected], Humboldt University of Berlin, Institute of Physics, Berlin, Germany
Holm Kirmse
Affiliation:
[email protected], Humboldt University of Berlin, Institute of Physics, Berlin, Germany
Ines Häeusler
Affiliation:
[email protected], Humboldt University of Berlin, Institute of Physics, Berlin, Germany
Changlin Zheng
Affiliation:
[email protected], Humboldt University of Berlin, Institute of Physics, Berlin, Germany
Anna Mogilatenko
Affiliation:
[email protected], Humboldt University of Berlin, Institute of Physics, Berlin, Germany
Get access

Abstract

Nanostructured materials from almost all classes of materials are of great interest because the reduced dimensionality may drastically change the physical properties. In general, these properties are a function of size, shape, arrangement and chemical composition of the nano-sized materials. Transmission electron microscopy (TEM) is a powerful tool to get a detailed insight into the material characteristics. To correlate microstructure as well as microchemistry and materials properties the various TEM techniques for imaging, diffraction and spectroscopy have to be combined. The potential applicability of quantitative TEM will be demonstrated for different nano-sized objects, particularly for semiconductor islands, nanowires, quantum dots and for soft magnetic materials. The classical diffraction contrast method of conventional TEM is applied to analyse the size, shape and arrangement of nano-sized structures, where a quantitative analysis often requires image simulations of diffraction contrast for theoretical structure models. An alternative and powerful method is the three-dimensional reconstruction of the shape from two-dimensional phase mapping by means of electron holography. This reqires the exact calculation of the mean inner potential of the specimen. Quantitative high-resolution transmission electron microscopy (qHRTEM) has to be applied to analyse structure and chemical composition on an atomic scale of magnitude. Particularly the application of aberration-corrected HRTEM offers new possibilities for quantitative structure analysis due to a contrast transfer by means of negative spherical aberration imaging (NCSI) and the resulting strong suppression of image delocalisation effects. An example for quantitative composition analysis will be demonstrated for ternary semiconductor quantum structures by means of a combined analysis of dark-field imaging and qHRTEM. The results will be compared with analytical TEM data (energy-dispersive X-ray spectroscopy (EDXS), electron energy-loss spectroscopy (EELS), and energy-filtered TEM (EFTEM)). The retrieval of chemical information with atomic resolution will be illustrated for III-V semiconductor nanostructures using STEM (scanning TEM) Z-contrast imaging. The correlation of structure and magnetic properties of soft magnetic materials will be demonstrated by combined application of Lorentz microscopy and electron holography. The potential applicability of the different quantitative TEM methods will be shown for following systems:

(i) (Si,Ge) islands

(ii) ZnTe and (Zn,Mn)Te nanowires

(iii) Ga(As,Sb) quantum dots (QDs) on GaAs substrate

(iv) nc softmagnetic FeCo alloys

The possibilities and limitations of the various methods applied will be critically evaluated.

Keywords

transmission electron microscopy (TEM)nanostructuresemiconducting
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1184: Symposium GG – Electron Crystallography for Materials Research and Quantitive Characterization of Nanostructured Materials , 2009 , 1184-GG03-02
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Zheng, Ch., Kirmse, H., Häusler, I., Scheerschmidt, K. and Neumann, W., Proc. 14th Europ. Micr. Congr., 2008, Aachen (Germany), Vol. 1: Instrumentations and methods, ed.: Luysberg, M., Tillmann, K., Weirich, Th., 287–288.Google Scholar
2 Kruse, P., Schowalter, M., Lamoen, D., Rosenauer, A. and Gerthsen, D., Ultramicroscopy 106, 105 (2006).Google Scholar
3 Rosenauer, A., Kaiser, S., Reisinger, T., Zweck, J., Gebhardt, W. and Gerthsen, D., Optik 101, 1 (1996).Google Scholar
4 Köhler, R., Neumann, W., Schmidbauer, M., Hanke, M., Grigoriev, D., Schäfer, P., Kirmse, H., Häusler, I. and Schneider, R., “Structural characterisation of quantum dots by X-ray diffraction and TEM“, Semiconductor Nanostructures, ed. Bimberg, D. (Springer, 2008) pp. 97–121.Google Scholar
5 Janik, E., Sadowski, J., Dłuzewski, P., Kret, S., Baczewski, L.T., Petroutchik, A., Łusakowska, E., Wróbel, J., Zaleszczyk, W., Karczewski, G., Wojtowicz, T., Presz, A., Appl. Phys. Lett. 89, 133114 (2006).Google Scholar
6 Kirmse, H., Neumann, W., Kret, S., Dluzewski, P., Janik, E., Karzewski, G. and Wojtowicz, T., phys. stat. sol. (c) 5, 3780 (2008).Google Scholar
7 Stranski, I.N., Krastanow, L.; Sitzungsberichte d. Akad. d. Wissenschaften in Wien, Abt. IIb, 146, 1937, S.797 Google Scholar
8 Häusler, I., Kirmse, H., Neumann, W., phys. stat. sol. (a) 205, 2598 (2008).Google Scholar
9 Herzer, G.. Physica Scripta. T49, 307 (1993).Google Scholar