Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-29T07:36:19.753Z Has data issue: false hasContentIssue false

Quantitative Investigation of the Factors Affecting the Hydrothermal Growth of Zinc Oxide Nanowires

Published online by Cambridge University Press:  31 January 2011

Aron Robert Rachamim
Affiliation:
[email protected], University of Cambridge, Electrical Engineering Division, Cambridge, United Kingdom
Sharvari H. Dalal
Affiliation:
[email protected], University of Cambridge, Electrical Engineering Division, Cambridge, United Kingdom
Sieglinde M.-L. Pfaendler
Affiliation:
[email protected], University of Cambridge, Electrical Engineering Division, Cambridge, United Kingdom
Michael E. Swanwick
Affiliation:
[email protected], University of Cambridge, Electrical Engineering Division, Cambridge, United Kingdom
Andrew Flewitt
Affiliation:
[email protected], University of Cambridge, Electrical Engineering Division, Cambridge, United Kingdom
William I. Milne
Affiliation:
[email protected], University of Cambridge, Electrical Engineering Division, Cambridge, United Kingdom
Get access

Abstract

Zinc oxide (ZnO) nanowires (NWs) are receiving significant industrial and academic attention for a variety of novel electronic, optoelectronic and MEMS device applications due to their unusual combination of physical properties, including being optically transparent, semiconducting and piezoelectric. Hydrothermal growth is possible at significantly lower temperatures (and hence lower thermal budgets) compared with other NW growth methods, such as chemical vapour deposition. In this context, the hydrothermal growth of ZnO NWs on seeded substrates immersed in equimolar zinc nitrate/HMTA aqueous solution was investigated. NWs were grown on polished silicon (001) substrates, and the solution concentrations, temperatures and growth times were varied. Importantly, the NW diameter was found to depend only on concentration during hydrothermal growth for times up to 4 hours. The average diameter was 14 nm in 0.005 M solution and increased up to a maximum 150 nm at 0.07 M, when the NWs formed a continuous polycrystalline film. Concentration and temperature were all found to affect the axial growth rate of NWs in the [0001] direction. The growth rate was constant up to 4 hours (200 nm hr-1) for constant conditions (81 oC, 0.025 M). The growth rate was found to increase approximately linearly with concentration at a rate of 7840 nm M-1 hr-1 up to 0.06 M (81 oC solution). The growth rate also increased linearly with temperature at a rate of 4.9 nm hr-1 K-1 (0.025 M solution). This indicates that growth takes place close to the equilibrium point, found by linear regression to be 36 oC for 0.025 M solution.

Type
Research Article
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Zhao, M. Wang, Z. and Mao, S.X.Piezoelectric Characterization of Individual Zinc Oxide Nanobelt Probed by Piezoresponse Force Microscope,” Nano Letters, vol. 4, Apr. 2004, pp. 587590.Google Scholar
[2] Song, J. Zhou, J. and Wang, Z.L.Piezoelectric and Semiconducting Coupled Power Generating Process of a Single ZnO Belt/Wire. A Technology for Harvesting Electricity from the Environment,” Nano Letters, vol. 6, 2006, pp. 16561662.Google Scholar
[3] Nadarajah, A. Word, R.C. Meiss, J. and Konenkamp, R.Flexible Inorganic Nanowire Light-Emitting Diode,” Nano Letters, vol. 8, Feb. 2008, pp. 534537.Google Scholar
[4] Johnson, J.C. Yan, H. Schaller, R.D. Haber, L.H. Saykally, R.J. and Yang, P.Single Nanowire Lasers,” The Journal of Physical Chemistry B, vol. 105, Nov. 2001, pp. 1138711390.Google Scholar
[5] Law, M. Greene, L.E. Johnson, J.C. Saykally, R. and Yang, P.Nanowire dye-sensitized solar cells,” Nat Mater, vol. 4, Jun. 2005, pp. 455459.Google Scholar
[6] Verges, M.A. Mifsud, A. and Serna, C.J.Formation of rod-like zinc oxide microcrystals in homogeneous solutions,” Journal of the Chemical Society, Faraday Transactions, vol. 86, 1990, pp. 959963.Google Scholar
[7] Greene, L.E. Yuhas, B.D. Law, M. Zitoun, D. and Yang, P.Solution-Grown Zinc Oxide Nanowires,” Inorganic Chemistry, vol. 45, 2006, pp. 75357543.Google Scholar
[8] Nakamura, Y. “Solution-Growth of Zinc Oxide Nanowires for Dye-Sensitized Solar Cells,” NNIN REU 2006 Research Accomplishments, NNIN, 2006.Google Scholar
[9] Guo, M. Diao, P. and Cai, S.Hydrothermal growth of well-aligned ZnO nanorod arrays: Dependence of morphology and alignment ordering upon preparing conditions,” Journal of Solid State Chemistry, vol. 178, Jun. 2005, pp. 18641873.Google Scholar