Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-17T17:06:41.887Z Has data issue: false hasContentIssue false

Quantitative Eels Microanalysis of Nanometre Sized Defects and Inclusions in Natural Diamond

Published online by Cambridge University Press:  28 February 2011

J. Bruley
Affiliation:
Now at IBM Research Division, Thomas J. Watson Research Center, P.O. Box 218 Yorktown Heights, NY 10598
L.M. Brown
Affiliation:
Cavendish Laboratory, Madingley Road, Cambridge, CB3 OHE, U.K.
Get access

Abstract

Electron energy loss spectroscopy of voidite defects in natural diamond shows that they are composed of nitrogen which is likely to be present in the form of solid N2 under high pressure (ca. 10 GPa). A similar examination of platelets has failed to reveal any nitrogen in them. It is proposed that the voidites are generated by a discontinuous precipitation mechanism as the platelets decompose. A similar study of the the chemistry of nanometre sized mineral particles present in most diamonds shows they are related to the earth's magma although there are notable differences.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Richardson, S.H., Nature, 322, 623, (1986)Google Scholar
2. Harris, J.W., Gurney, J.J., in The Properties of Diamond, ed. Field, J.E. (Academic Press, 1979), p. 555.Google Scholar
3. Navon, O., Huttcheon, I.D., Rossman, G.R. & Wasserburg, G.J., Nature, 335, 784 (1988); A.R. Lang & J. Walmsley, J C. Phys. Chem. Miner., 9, 6 (1983)Google Scholar
4. Evans, T., Cont. Phys., 17, 45 (1976)CrossRefGoogle Scholar
5. Hirsch, P.B., Pirouz, P. & Barry, J.C., Proe. Roy. Soc. Lond., A407, 239 (1986)Google Scholar
6. Barry, J.C., Bursill, L.A., Hutchinson, J.J., Lang, A.R., Rackham, G.M., & Sumida, N., Phil. Trans. Roy. Soc. Lond., A321, 361 (1987)Google Scholar
7. Bruley, J. & Brown, L.M., Phil. Mag., (Accepted for publication)Google Scholar
8. Egerton, R.F., Electron Energy Loss Spectroscopy in the Electron Microscope, (Plenum Press, New York, 1986)Google Scholar
9. Mills, R.L., Bronson, J.C., J. Chem. Phys., 63, 4026 (1975)Google Scholar
10. Sodhi, R.N.S. & Brion, C.E., J. Elec. Spec. & Rel. Phen., 36 187 (1985); A.P. Hitchcock & C.E. Brion, ibid., 18, 1 (1980)CrossRefGoogle Scholar
11. Berger, S.D. & Pennycook, S.J., Nature, 198, 635 (1982)Google Scholar
12. Lang, A.R., Proc. Phys. Soc., A340, 233 (1964)Google Scholar
13. Humble, P., Mackenzie, J.K. & Olsen, A., Phil. Mag., A52, 605 (1985)CrossRefGoogle Scholar
14. Woods, G.S., Proc. Roy. Soc., A407, 219 (1986)Google Scholar
15. Porter, D.A. & Easterling, K.E., Phase Transitions in Metals and Alloys, (Van Nostrand Reinold, New York, 1981), p323 Google Scholar
16. Meyer, H.O.A. & Boyd, F.R., Geo. Cos. Acta, 36, 1255 (1975); Y.L. Orlov, The Mineralogy of Diamond, (J. Wiley, New York, 1977)Google Scholar