Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-19T06:51:50.174Z Has data issue: false hasContentIssue false
  • English
  • Français

Proton Modification of Ultra High Molecular Weight Polyethylene to Promote Crosslinking for Enhanced Chemical and Physical Properties

Published online by Cambridge University Press:  21 February 2011

J.F. Wilson ,
J.R. Liu ,
F. Romero-Borja  and
W.K. Chu
J.F. Wilson
Affiliation:
Texas Center for Superconductivity, University of Houston, Houston, Texas 77204–5932
J.R. Liu
Affiliation:
Texas Center for Superconductivity, University of Houston, Houston, Texas 77204–5932
F. Romero-Borja
Affiliation:
Texas Center for Superconductivity, University of Houston, Houston, Texas 77204–5932
W.K. Chu
Affiliation:
Texas Center for Superconductivity, University of Houston, Houston, Texas 77204–5932
Get access

Abstract

Crosslinking onset was investigated for ultra high molecular weight polyethylene(UHMW-PE) implanted with 2.6 MeV H+ ions at low doses from 6×1011-3×1013 ions/cm2. Crosslinking in the near surface region(20–40μm) was determined from gel permeation chromatography(GPC) of 1,2,4 trichlorobenzene sol fractions and increased with dose. Fourier transform infrared spectroscopy(FTIR) showed irradiation resulted in increased free radicals confirmed from increased carbonyl groups. Hydrogen annealing after ion implantation resulted in 38–49% decrease in FTIR peak associated with carbonyl.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 396: Symposium A – Ion-Solid Interactions for Materials Modification and Processing , 1995 , 311
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Saunders, K. J., Organic Polymer Chemistry, Chapman and Hall Ltd., London, 1973.Google Scholar
2 Franck, A., Kurth, M., and Eyerer, P., in Ultra-High Molecular Weight Polyethylene as Biomaterial in Orthopedic Surgery, edited by Willert, H. -G., Buchorn, G. H., and Eyerer, P., Hogrefe ' Huber Publishers, Toronto, 1991, p. 15.Google Scholar
3 Jahan, M. S., Wang, C., Schwartz, G., and Davidson, J. A., J. of Biomedical Mater. Res.,Vol. 25, pp. 1005–1017, 1991.Google Scholar
4 Topchiev, A. V., Krentsel, B. A., and Norris, A. D., Polyolefines, Pergamon Press Inc., New York, 1962 Google Scholar
5 Venkatesan, T., Nuclear Instruments and Methods in Physics Research, B7/8, pp. 461–467, (1985).Google Scholar
6 Calcagno, L., Compagnini, G., and Foti, G., Nuclear Instruments and Methods in Physics Research, B65, pp. 413–422, (1992).Google Scholar
7 Sangster, D. F., Irradiation of Polymeric Materials, American Chemical Society, Washington D.C., 1993, pp. 95–102.Google Scholar
8 Streicher, R. M., in Ultra-High Molecular Weight Polyethylene as Biomaterial in Orthopedic Surgery, edited by Willert, H. -G., Buchorn, G. H., and Eyerer, P., Hogrefe ' Huber Publishers, Toronto, 1991, p. 66.Google Scholar
9 Ishitani, A., Shoda, K., Ishida, H., Watanabe, T., and Yoshida, K., Nuclear Instruments and Methods in Physics Research, B39, pp. 783–786, (1989).Google Scholar
10 Lee, E. H., Rao, G. R., Lewis, M. B., and Mansur, L. K., J. Mater. Res., Vol. 9, No. 4, pp. 1043–1050,(1994).Google Scholar
11 Rao, G. R., Lee, E. H., Bhattacharya, R., and McCormick, A. W., J. Mater. Res., Vol. 10, No. 10, pp. 190–201,(1995).Google Scholar
12 Rao, G. R., Lee, E. H., and Mansur, L. K., Wear, 174, pp. 103–109,(1994).Google Scholar
13 Puglisi, O., Licciardello, A., Calcagno, L., and Foti, G., Nuclear Instruments and Methods In Physics Research, B19/20, pp. 865–871,(1987).Google Scholar
14 Koenig, J. L., Spectroscopy of Polymers, American Chemical Society, Washington D.C., 1992.Google Scholar
15 Blunn, G. W., Joshi, A. B., Lilley, P. A., Engelbrecht, E., Ryd, L., Lidgren, L., Hardinge, K., Nieder, E., and Walker, P. S., Acta Orthop Scand, 63(3), pp. 247–255, (1992).Google Scholar
16. Ziegler, J. F., Biersack, J. P., and Littmark, U., The Stopping and Range of Ions in Solids, Pergamon Press, Oxford, 1985, Vol. 1.Google Scholar
17 Kurth, M. and Eyerer, P., in Ultra-High Molecular Weight Polyethylene as Biomaterial in Orthopedic Surgery, edited by Willert, H. -G., Buchorn, G. H., and Eyerer, P., Hogrefe ' Huber Publishers, Toronto, 1991, p. 82.Google Scholar
18 du Plessis, T.A., Grobbelaar, C.J., and Marais, F., Radiation Phys. Chem., Vol. 9, pp. 647–652, (1977).Google Scholar