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Preparation and Characterization of (C4H9NH3)2MCl4 (M=Mn, Cu)

Published online by Cambridge University Press:  01 February 2011

Liling Guo ,
Yadong Dai ,
Mingjie Hu ,
Hanxing Liu  and
Shixi Ouyang
Liling Guo
Affiliation:
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China
Yadong Dai
Affiliation:
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China
Mingjie Hu
Affiliation:
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China
Hanxing Liu
Affiliation:
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China
Shixi Ouyang
Affiliation:
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China
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Abstract

With the preparation of organic-inorganic layered perovskite-type compounds (C4H9NH3)2MCl4 (M = Mn, Cu) in solutions, X-ray diffraction (XRD), scanning electron microscopy (SEM), thermal gravimetry (TG) and differential scanning calorimetry (DSC) have been used to characterize the obtained powders. XRD patterns demonstrate that the two compounds have obvious layered structures and SEM pictures reveal that both (C4H9NH3)2MnCl4 and (C4H9NH3)2CuCl4 take on obvious sheet-like microstructure. TG&DSC curves indicate that (C4H9NH3)2CuCl4 decomposes at much lower temperature than (C4H9NH3)2MnCl4.This is ascribed to weakening interactions between its organic and inorganic components, which is presumably due to the Jahn-Teller distortion of [CuCl6] octahedra.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 848: Symposium FF – Solid-State Chemistry of Inorganic Materials V , 2004 , FF9.30
Copyright
Copyright © Materials Research Society 2005

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References

REFERENCES

1. Sekine, Taketoshi, Okuno, Tsynehisa, Awaga, Kunio “Magmetoc behavior of the layered perovskite ferromagnet (p-cyanoanilinum+)2CuCl4 2- under hydrostatic pressure” Chemical Physics Letters 249(1996)201–204 Google Scholar
2. Wortham, Etienne, Zorko, Andrej, Arcon, Denis, Lappas, Alexandros “Organic-inorganic perovskites magnetic nanocomposites”, Physica B 319(2002 387–391)Google Scholar
3. Mitzi, David B. “Templating and structural engineering in organic-inorganic perovskites” J. Chem. Soc., Dalton Trans., 2001, 1–12 Google Scholar
4. Haddad, Salim, Willett, Roger D. “Polymorphism in Bis (4-dimethylamino-pyridinium) tetrachlorlcuprate (II)” Inorg. Chem. 2001, 40, 2457–2460 Google Scholar
5. Zhou, Gongdu, Duan, Lianyun “Structural Chemistry Foundation” (Book) Beijing University Press (2002) Page 332 Google Scholar