Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-29T08:21:43.619Z Has data issue: false hasContentIssue false

Positron state and Lifetime in C60/C70 Fullerites

Published online by Cambridge University Press:  25 February 2011

H.-E. Schaefer
Affiliation:
Universität Stuttgart, Institut für Theoretische und Angewandte Physik, PfafFenwaldring 57, 7000 Stuttgart 80, Germany
M. Forster
Affiliation:
Universität Stuttgart, Institut für Theoretische und Angewandte Physik, PfafFenwaldring 57, 7000 Stuttgart 80, Germany
R. WÜrschum
Affiliation:
Universität Stuttgart, Institut für Theoretische und Angewandte Physik, PfafFenwaldring 57, 7000 Stuttgart 80, Germany presently at: Massachusetts Institute of Technology, Dep. Materials Science and Engin., Cambridge, MA 02139, USA
F. Banhart
Affiliation:
Max-Planck-Institut für Metallforschung, Institut fur Physik, Heisenbergstr. 1, 7000 Stuttgart 80, Germany
Get access

Abstract

The present paper reports on positron lifetime measurements on Ceo/C 70 fullerite powder as a function of temperature and quasi-hydrostatic pressure in order to give an estimate of the positron annihilation site in the fullerite lattice. A single-component positron lifetime of 402 ps is observed which significantly decreases under quasi-hydrostatic pressure. From this and the soft intermolecular properties of the fullerites one can conclude that the positron is annihilated rather in the intermolecular space than inside the fullerene molecules. However, positron trapping at lattice defects, which are observed by high-resolution electron microscopy, cannot be ruled out.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Kroto, H.W., Heath, J.R., O'Brien, S.C., Curl, R.F., Smalley, R.E., Nature L18, 162 (1985)CrossRefGoogle Scholar
2. Kriitschmer, W., Lamb, L.D., Fostiropoulos, K., Huffman, D.R., Nature 347, 354 (1990)CrossRefGoogle Scholar
3. Electrical, Optical and Magnetic Properties of Organic Solid State Materials, edited by Chiang, L.Y., Garito, A.F., Sandman, D.J. (Mater.Res.Soc.Proc. 247 Pittsburgh, PA, in press)Google Scholar
4. Diederich, F. and Whetten, R.L., Angew. Chemie 103, 695 (1991)CrossRefGoogle Scholar
5. Heiney, P.A., Fischer, J.E., McGhie, A.R., Romanow, W.J., Denenstein, A.M., McCauley, J.P., Smith, A.B. III, Cox, D.E., Phys. Rev. Lett. 66, 2911 (1991)CrossRefGoogle Scholar
6. Guo, Y., Karasawa, N., Goddard, W.A., Nature 351, 464 (1991)Google Scholar
7. Dravid, V.P., Liu, S., Kappes, M.M., Chem. Phys. Lett. 185, 75 (1991)CrossRefGoogle Scholar
8. Tendeloo, G. Van, Beeck, M. op de, Amelinckx, S., Bohr, J., Kritschmer, W., Europhys. Lett. 15, 295 (1991)CrossRefGoogle Scholar
9. Banhart, F., Forster, M., Kriitschmer, W., Schaefer, H.-E., Phil.Mag.Lett., to be publ.Google Scholar
10. Schaefer, H.-E., phys. stat. sol. (a) 102, 47 (1987)CrossRefGoogle Scholar
11. Puska, M.J. and Nieminen, R.M., J.Phys.Condens.Matter 4 (1992) L149 CrossRefGoogle Scholar
12. Azuma, T., Saito, H., Yamazeki, Y., Komeki, K., Nagashima, Y., Watanabe, H., Hyodo, T., Kataura, H., Kobayashi, N., J. Phys. Soc. Jap. 6, 2812 (1991)Google Scholar
13. Hasegawa, M., Kajino, M., Kuwahara, H., Kuramoto, E., Takenaka, M., Yamaguchi, S., Mat. Science Forum, in pressGoogle Scholar
14. Zhang, Q.M., Yi, Z.Y., Bernholc, J., Phys. Rev. Lett. 66. 2633 (1991)CrossRefGoogle Scholar
15. Duclos, S.J., Brister, K., Haddon, R.C., Krotan, A.R., Thiel, F.A., Nature 351, 380 (1991)CrossRefGoogle Scholar
16. Ruoff, R.S. and Ruoff, A.L., Nature 350, 663 (1991)CrossRefGoogle Scholar
17. Puska, M.J. and Corbel, C., Phys. Rev. B 38, 9874 (1988)Google Scholar
18. Khanna, S.N., Rao, B.K., Jena, P., Esterling, D., Puska, M.J., Phys. Rev. B 37, 6 (1988)Google Scholar
19. Puska, M.J., Miikinen, S., Manninen, M., Nieminen, R.M., Phys. Rev. B39, 7666 (1989)CrossRefGoogle Scholar