Hostname: page-component-cd9895bd7-p9bg8 Total loading time: 0 Render date: 2024-12-24T00:25:21.632Z Has data issue: false hasContentIssue false
  • English
  • Français

Porous Metal Oxides as Catalysts

Published online by Cambridge University Press:  21 May 2012

Boxun Hu ,
Christopher Brooks ,
Eric Kreidler  and
Steven L. Suib
Boxun Hu
Affiliation:
Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USA.
Christopher Brooks
Affiliation:
Honda Research Institute USA, Inc. 1381 Kinnear Rd. Suite 116, Columbus, OH 43212, USA.
Eric Kreidler
Affiliation:
Honda Research Institute USA, Inc. 1381 Kinnear Rd. Suite 116, Columbus, OH 43212, USA.
Steven L. Suib
Affiliation:
Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USA. Department of Chemistry, University of Connecticut, Storrs, CT 06269, USA.
Get access

Abstract

Porous CoO/Mn2O3 Fischer-Tropsch (F-T) catalysts have been studied in CO hydrogenation. These CoO/Mn2O3 catalysts have been synthesized by incipient wetness impregnation method. These mesoporous catalysts have pore diameters of 2-25 nm and a surface area of 9.0 m2/g. The gas and liquid products have been analyzed by an online gas chromatograph. The solid products were characterized by gas chromatograph-mass spectroscopy. These microsize cobalt catalysts exhibit good activity with 72.1% CO conversion and they are very stable in a 48 h stream test at 280ºC. The selectivity to paraffins is above 95%. Few wax products were synthesized with a yield of less than 2%. The size effects of the cobalt catalysts have been studied by scanning electron microscopy.

Keywords

catalyticMnCo
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1446: Symposium U – Materials for Catalysis in Energy , 2012 , mrss12-1446-u08-07
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Mcmahon, K. C., Suib, S. L., Johnson, B. G., Bartholomew, C. H., J. Catal. 106, 47–53 (1987).Google Scholar
2. Suib, S. L., Mcmahon, K. C., Tau, L. M., Bennett, C. O., J. Catal. 89, 20–34 (1984).Google Scholar
3. Kruse, N., Schweicher, J., Bundhoo, A., Frennet, A., de Bocarme, T. V., Top. Catal. 48, 145–152 (2008).Google Scholar
4. Davis, B. H., Ind. Eng. Chem. Res. 46, 8938–8945 (2007).Google Scholar
5. Fischer, F., Tropsch, H., Brennst. Chem. 7, 97–116 (1926).Google Scholar
6. Keyser, M. J., Everson, R. C., Espinoza, R. L., Appl. Catal. A 171, 99–107, (1998).Google Scholar
7. Ojeda, M., Granados, M. L., Rojas, S., Terreros, P., Garcia-Garcia, F. J., Fierro, L.G., Appl. Catal. A 261, 47–55 (2004).Google Scholar
8. Karaca, H., Hong, J. P., Fongarland, P., Roussel, P., Griboval-Constant, A., Lacroix, M., Hortmann, K., Safonova, O. V., Khodakov, A. Y., Chem. Commun. 46, 788–790 (2010).Google Scholar
9. den Breejen, J. P., Radstake, P. B., Bezemer, G. L., Bitter, J. H., Froseth, V., Holmen, A., de Jong, K. P., J. Am. Chem. Soc. 131, 7197–7203 (2009).Google Scholar