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Porosity and its Relationship to the Strength of Hydraulic Cement Pastes

Published online by Cambridge University Press:  22 February 2011

K Kendall
Affiliation:
ICI New Science Group, The Heath, Runcorn, Cheshire, UK
J D Birchall
Affiliation:
ICI New Science Group, The Heath, Runcorn, Cheshire, UK
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Abstract

The concept of ‘intrinsic strength’ of cement was addressed by testing the bending strength propertes of MDF cement pastes[1–5], containing no organic material, over a range of pore volumes and flaw lengths. The MDF pastes, made only of cement and water, exhibited interesting behaviour, particularly the well packed compositions which gave remarkably low porosity, about 1%, and high modulus, 75 GPa. It was demonstrated that the bending strength of these materials depended on flaw size in a brittle fashion, and that the toughness increased as the volume porosity fell. Fracture mechanics described the results satisfactorily. Therefore, theories based on intrinsic strength, or on the need for polymers to provide high strength [7, 10] are unnecessary.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

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References

1. Birchall, J D, Howard, A Jand Kendall, K Nature 289, 388 (1981)10.1038/289388a0CrossRefGoogle Scholar
2. Birchall, J D, Howard, A J and Kendall, K European Patent Publication No 0021682 (1981).Google Scholar
3. Birchall, J D, Howard, A Jand Kendall, K Proc Brit Ceram Soc 32, 25 (1982).Google Scholar
4. Birchall, J D, Howard, A J, Kendall, Kand Raistrick, J H European Patent Publication No 0055035 (1982).Google Scholar
5. Kendall, K, Howard, A J and Birchall, J D Phil Trans R Soc A 310, 139 (1983).10.1098/rsta.1983.0073Google Scholar
6. Powers, T C Proc 4th Int Symp Chemistry of Cement Nat Bur Stds No 43 Vol II (Washington DC 1960) p577.Google Scholar
7. Eden, N.B. and Bailey, J E J Mater Sci. 19, 2677 (1984).10.1007/BF00550825CrossRefGoogle Scholar
8. Bailey, J Eand Higgins, D D Nature 292, 89 (1981).10.1038/292089a0CrossRefGoogle Scholar
9. Neville, A M Properties of Concrete (Pitman London 1977) p241.Google Scholar
10. Higgins, D Dand Bailey, J E J Mater Sci. 11, 1995 (1976)10.1007/PL00020325CrossRefGoogle Scholar
11. Wright, W and Byrne, J G Nature 203, 1374 (1964).10.1038/2031374a0CrossRefGoogle Scholar
12. Kendall, K Physics and Chemistry of Porous Media (ed Johnson, D L and Sen, P N) AIP No 107 (AIP New York 1984) p78.Google Scholar
13. Kendall, K Contemporary Physics 21, 277 (1980)10.1080/00107518008210960CrossRefGoogle Scholar
14. Hansen, T C J Am Concr Inst 62, 193 (1965).Google Scholar
15. Helmuth, R A and Turk, D A Symp on Struct of Portland Cement Paste and Concrete No 90 (Washington: Highway Res Board 1966) 135.Google Scholar
16. Lawrence, C.D. Res. Rep. Cem. Concr. Ass. No 19 (1969).Google Scholar
17. Roy, D.M. and Gouda, G.R. Cem. Concr. Res 5, 153 (1975).10.1016/0008-8846(75)90073-3CrossRefGoogle Scholar