Published online by Cambridge University Press: 17 March 2011
Room temperature and low temperature photoluminescence studies of AlxGa1−xN/GaN superlattices reveal a red shift of the dominant transition band relative to the bulk GaN bandgap. The shift is attributed to the quantum-confined Stark effect resulting from polarization fields in the superlattices. A theoretical model for the band-to-band transition energies based on perturbation theory and a variational approach is developed. Comparison of the experimental data with this model yields a polarization field of 4.6 × 105 V/cm for room temperature Al0.1Ga0.9N/GaN and 4.5 × 105 V/cm for room temperature Al0.2Ga0.8N/GaN. At low temperatures the model yields 5.3 × 105 V/cm for Al0.1Ga0.9N/GaN and 6.3 × 105 V/cm for Al0.2Ga0.8N/GaN. The emission bands exhibit a blue shift at high excitation densities indicating screening of internal polarization fields by photo-generated free carriers.