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Platinum Clusters with Phosphide Ligands: Synthesis and Characterization

Published online by Cambridge University Press:  15 February 2011

Ilya I. Moiseev ,
N. Yu. Kozitsyna ,
D. I. Kochubey  and
K. I. Zamaraev
Ilya I. Moiseev
Affiliation:
Institute of General & Inorganic Chemistry, Russian Academy of Sciences, Moscow
N. Yu. Kozitsyna
Affiliation:
Institute of General & Inorganic Chemistry, Russian Academy of Sciences, Moscow
D. I. Kochubey
Affiliation:
Institute of Catalysis, Russian Academy of Sciences, 630090 Novosibirsk
K. I. Zamaraev
Affiliation:
Institute of Catalysis, Russian Academy of Sciences, 630090 Novosibirsk
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Extract

Reduction of triphenylphosphine-containing Pt(II) complexes with H2, HCOOH and Na-amalgam was studied to compare the results with those for similar reductions of analogous Pd(II) complexes. Clusters of compositions [Pt(PPh2)]n, n=6–10, have been found to be the products of the reduction reactions under consideration.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 272: Symposium O – Chemical Processes in Inorganic Materials: Metal and Semiconductor Clusters , 1992 , 91
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Vargaftik, M.N., Zagorodnikov, V.P., Stolarov, I.P., Moiseev, I.I., Kochubey, D.I., Likholobov, V.A., Chuvilin, A.L., Zamaraev, k.I., J.Molec.Cat.53, 315 (1989).Google Scholar
2. Berenblyum, A.S., Kniznik, A.G., Mund, S.L., Moiseev, I.I., J.Organomet.Chem. 234, 219 (1982).CrossRefGoogle Scholar
3. Dobson, A., Robinson, S.P., Platinum Met. Rev., 1976, 20, 56; A. S. Berenblum, T.G. Goranskaya, S.L. Mund, I.I. Moiseev, Izv.Akad. Nauk SSSR, Ser.Khim. 1979, (6), 1387.Google Scholar
4. Hartley, F.R., Searle, G.W., Inorg.Chem.12, 1949 (1973).Google Scholar
5. Powell, J., Jack, T., Inorg.Chem. 11, 1039 (1972).Google Scholar
6. Bhaduri, S., Sharma, K., Jones, P.J., Erdbrugger, C.F.,.J.Organomet. Chem. 326, C46–48 (1987).CrossRefGoogle Scholar
7. Burrows, A.D., Jeffrey, J.G., Machell, J.C., Mingos, D.M.P., J.Organomet. Chem. 406, 399 (1991).CrossRefGoogle Scholar
8. Kozitsyna, N.Yu., Dikareva, L.M., Andrianov, V.I., Zinchenko, S.V., Khutoryanskii, V.A., Schmidt, F.K., Porai-Koshits, M.A., Moiseev, I.I., Izv.Akad. Nauk SSSR, Ser.Khim. 1988, (8), 1894.Google Scholar
9. Kozitsyna, N. Yu., Surashskaya, M V., Larina, T. B., Kozmin, P. A., Kotelnikova, A. C., Moiseev, I. I., Izv.Akad. Nauk SSSR, Ser.Khim. 1989, (7), 1894.Google Scholar
10. Kozitsyna, N.Yu., Ellern, A.M., Antipin, M.Yu., Struchkov, Yu.T., Moiseev, I.I., Mendeleev Commun., 1991, (3), 92.Google Scholar
11. Hursthouse, M.B., Sloan, O.D., Thornton, P., Walker, N.P.C., Polyhedron 5(9), 1475 (1986).Google Scholar