Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-19T22:50:59.626Z Has data issue: false hasContentIssue false

Pillaring of Layered Double Hydroxides With Cage-Like Polysilicates: a Possible New Class of Base Catalysts or Catalyst Precursors

Published online by Cambridge University Press:  21 February 2011

Colin A. Fyfe
Affiliation:
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1
Guoyi Fu
Affiliation:
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1
Hiltrud Grondey
Affiliation:
Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, BC, Canada V6T 1Z1
Get access

Abstract

Pillaring of highly basic layered double hydroxides (MgnAl(OH)2n+2Cl, n=2–5) with octameric polysilicate (Si8O208-) has been achieved via a direct ion exchange route.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Cavani, F., Trifiro, F. and Vaccari, A., Catalysis Today 11, 173 (1991).Google Scholar
2 Reichle, W.T., Chemtech. 58 (1986).Google Scholar
3 De Roy, A., Forano, C., El Malki, K. and Besse, J.-P., in Synthesis of Microporous Materials Vol. II;. edited by Occelli, M.L. and Robson, H. (Van Nostrand Reinhold, New York, 1992), pp. 108169.Google Scholar
4 Jones, W and Chibwe, M., in Pillared Layered Structures, edited by Mitchell, I.V. (Elsevier Applied Science, London, 1990), pp. 6777.Google Scholar
5 Pinnavaia, TJ., Kwon, T. and Yun, S.K., NATO ASI Series, Ser. C. 352, 91 (1992).Google Scholar
6 Engelhardt, G. and Michel, D., High-Resolution Solid-State NMR of Silicates and Zeolites. (John Wiley & Sons, Chichester, 1987), pp. 75105.Google Scholar
7 Smolin, Yu.I., Shepelev, Yu.F., Pomes, R., Hoebbel, D. and Wieker, W., Sov. Phys. Crystallogr. 24, 19 (1979); M.Wiebcke, M.Grube, H.Koller, G.Engelhardt and J.Felsche, J. Microporous Mater. 2,55 (1993).Google Scholar
8 Drezdon, M.D., Inorg. Chem. 27, 4628 (1988).Google Scholar
9 Reichle, W.T., J. Cat 94, 547 (1985); C.P.Kelkar, A. Schutz and G.Marcelin, in Perspectives in Molecular Sieve Science, edited by W.F.Flank and T.E.WhyteJr., (ACS, Washington, 1988), pp. 324–334.Google Scholar