Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-25T15:42:38.788Z Has data issue: false hasContentIssue false
  • English
  • Français

The Physical Chemistry of Inoculation of Cast Iron

Published online by Cambridge University Press:  21 February 2011

M. A. Gadd  and
G. H. J. Bennett
M. A. Gadd
Affiliation:
Department of Metallurgy & Materials, University of Birmingham, U.K.
G. H. J. Bennett
Affiliation:
Department of Metallurgy & Materials, University of Birmingham, U.K.
Get access

Abstract

A theoretical analysis of inoculation shows that homogeneous nucleation of CaO, CaS, Al2O3 and ZrO2 is possible arid subsequent heterogeneous nucleation of silicates yields substrates for graphite growth. Excessive silicate growth leading to separation of nuclei could result in fade.

Results show that CaO/CaS embyros are most effective via silicate formation, Zr and Al control fade arido xidation enhances inoculation and fade. Added stable oxides give only limited inoculation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 34: Symposium – Physical Metallurgy of Cast Iron , 1984 , 99
Copyright
Copyright © Materials Research Society 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Patterson, V.H., Foundry T. Jnl., 139, 91, July 1973 and Castings, 16 May-June (1976).Google Scholar
2. Winegard, W.C., An Introduction to the Solidification of Metals, Inst. of Metals Monograph 29, (The Metals Society, London 1964).Google Scholar
3. Turpin, M.L. and Elliott, J.F., J.I.S.I., 204, 217, (1966).Google Scholar
4. Minkoff, I., The Physical Metallurgy of Cast Iron (John Wiley & Sons, Chichester 1983).Google Scholar
5. Turkdogan, E.T., J.I.S.I., 204, 914 (1966).Google Scholar
6. Gibbs, J.W., The Scientific Papers, 257 (Dover Publications Inc., New York 1951).Google Scholar
7. Volmer, M. and Weber, A., Z. Phys. Chem., 119, 277 (1926).CrossRefGoogle Scholar
8. Becker, R., Annal. Phys., 32, 128 (1938).10.1002/andp.19384240115CrossRefGoogle Scholar
9. Gadd, M.A., Ph. D. Thesis, University of Birmingham, U.K. (1983).Google Scholar
10. Elliott, J.F. et al., eds. Thermochemistry for Steelmaking, vol.2, (Pergamon Press, Oxford 1963).Google Scholar
11. Samsonov, G.V., The Oxide Handbook,, (I.F.I. Plenum, 1973).10.1007/978-1-4615-9597-7CrossRefGoogle Scholar
12. Livey, D.W. and Murray, P., J.A.C.S., 39, 363 (1956).Google Scholar
13. Parikh, N., J.A.C.S, 41, 18 (1958).Google Scholar
14. Selcuk, E. and Kirkwood, D.H., J.I.S.I., 211, 130 (1973).Google Scholar
15. Straube, H. et al., Archiv. f. d. Eisenh., 38, 509 (1967).10.1002/srin.196704217Google Scholar
16. Smithells, C.J., Metals Reference Book, 4th Editn., (Butterworths, London 1967).Google Scholar
17. Kiessling, R. and Lange, N., Non-metallic Inclusions in Steels, 2nd Editn. Book No. 194 (The Metals Society, London 1978).Google Scholar
18. Kubaschewski, O. and Alcock, C.B., Metallurgical Thermochemistry, 5th Editn., (Pergamon Press, Oxford 1979).Google Scholar
19. Forster, E. and Richter, H., Production and Application of Clean Steels, Book No. 134, 24 (The Metals Society, London 1972).Google Scholar
20. Lindborg, U. and Torsell, K., Trans. Met. Soc. A.I.M.E., 242, 94 (1968).Google Scholar
21. Kozakevitch, P. and Olette, M., Production anid Application of Clean Steels, Book No. 143, 42 (The Metals Society, London 1972).Google Scholar
22. Kawai, M. and Kobayashi, S., Tetsu-to-Hagane, 52, 546 (1966).Google Scholar
23. Nakanishi, K. and Ooi, H., Tetsu-to-Hagane, 55, 460 (1969)10.2355/tetsutohagane1955.55.6_460CrossRefGoogle Scholar
24. Zehtab-Jahedi, M. and Kondic, V., Solidification Technology in the Foundry and Cast House, Book No. 273, 555 (The Metals Society, London 1982).Google Scholar
25. Basdogan, M.F., Kondic, V. and Bennett, G.H.J., Trans. A.F.S., 90 Paper 47 (1982).Google Scholar
26.. Thyberg, B. and Granehult, O, 37th Int. Foundry Cong., Chicago, Paper 4 (A.F.S. 1970).Google Scholar
27. Hall, D. and Bennett, G.H.J., J.I.S.I., 205, 309 (1967).Google Scholar
28. de Sy, A., Trans. A.F.S., 75 161 (1967).Google Scholar
29. Basdogan, M.F., Bennett, G.H.J. and Kondic, V., Solidification Technology in the Foundry and Cast House, Book No. 273, 240 (The Metals Society, London 1982).Google Scholar
30. Muzumda, K.M. and Wallace, J.F., Trans. A.F.S., 81, 412 (1973).Google Scholar
31. Quintero-Nunez, M. and Kondic, V., I.B.F. Jnl., 77 220 (1984).Google Scholar