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Photoelectron Spectroscopy of Si2

Published online by Cambridge University Press:  28 February 2011

Theofanis N. Kitsopoulos  and
Daniel M. Neumark
Theofanis N. Kitsopoulos
Affiliation:
Department of ChemistryUniversity of California at BerkeleyBerkeley CA 94720
Daniel M. Neumark
Affiliation:
Department of ChemistryUniversity of California at BerkeleyBerkeley CA 94720
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Abstract

In this report we discuss the photoelectron spectrum of Si2− obtained at 355 nm. The spectrum shows a series of transitions to the low-lying triplet states of Si2 as well as transitions to the higher-lying singlet states. Several possible assignments of the anion and neutral triplet states are presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 206: Symposium G – Clusters and Cluster-Assembled Materials , 1990 , 71
Copyright
Copyright © Materials Research Society 1991

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References

REFERENCES

1. Metal Clusters, edited by Moskovits, M. (Wiley, New York, 1986);Google Scholar
Schumacher, E., Kappes, M., Marti, K., Radi, P., Scär, M., and Schmidhalter, B., Ber. Bunsenges. Phys. Chem. 88, 220 (1984).Google Scholar
2. Bier, K.D., Haslett, T.L., Kirkwood, A.D. and Moskovits, M., Faraday Discuss. Chem Soc. 86. 181 (1988).CrossRefGoogle Scholar
3. Herrmann, A., Hofmann, M., Leutwyler, S., Schumacher, E., and Wöste, L., Chem. Phys. Lett. 62, 216 (1979);CrossRefGoogle Scholar
Gole, J. L., Pace, S.A., Preuss, D.R., and Green, G.J., J. Chem. Phys. 76, 2247 (1982) ;Google Scholar
Delacrétez, G., Grant, E.R., Whetten, R.L., Wöste, L. and Zwanziger, J.W., Phys. Rev. Lett. 56, 2598 (1986).Google Scholar
4. Morse, M.D., Hopkins, J.B., Langridge-Smith, P.R., and Smalley, R.E., J. Chem. Phys. 79, 5316 (1983) ;Google Scholar
Rohlfing, E.A., and Valentini, J.J, Chem. Phys. Lett. 126, 113 (1986);Google Scholar
J. Chem. Phys. 84, 6560 (1986);Google Scholar
Fu, Z., Lemire, G.W., Hamrick, Y.M., Taylor, S., Shui, J.C., and Morse, M.D., J. Chem. Phys. 88. 3524 (1988);Google Scholar
LaiHing, K., Cheng, P.Y., and Duncan, M.A., Z. Phys. D 13, 161 (1989)Google Scholar
5. Leopold, D.G., and Lineberger, W.C., J. Chem. Phys. 85. 51 (1986);Google Scholar
Ervin, K. M., Ho, J., and Lineberger, W.C., J. Chem. Phys. 89, 4514 (1988).Google Scholar
6. Snodgrass, J.T., Coe, J.V., Freidhoff, C.B., Mchugh, K.M., and Bowen, K.H., Faraday Discuss. Chem. Soc. 86. 241 (1988);CrossRefGoogle Scholar
7. Ganteför, G., Gausa, M., Meiwes-Broer, K.H., and Lutz, H.O., Z. Phys. D 9, 253 (1988);Google Scholar
Faraday Discuss. Chem. Soc. 86, 197 (1988).Google Scholar
8. Cheshnovsky, O., Yang, S.H., Pettiette, C. L., Craycraft, M.J., Liu, Y., and Smalley, R.E., Chem. Phys. Lett. 138, 119 (1987);Google Scholar
Yang, S.H., Pettiette, C.L., Conceicao, J., Cheshnovsky, O., and Smalley, R.E., Chem. Phys. Lett. 139, 119 (1987);Google Scholar
Taylor, K.J., Pettiette, C.L., Craycraft, M.J., Cheshnovsky, O., and Smalley, R.E., Chem. Phys. Lett. 152, 347 (1988).Google Scholar
9. Kitsopoulos, T.N., Chick, C.J., Weaver, A. and Neumark, D.M., J. Chem. Phys. 93, 6108 (1990)Google Scholar
10. Huber, K.P., and Herzberg, G., Molecular Spectra and Molecular Structure IV, Constants of Diatomic Molecules, (Van Nostrand Reinhold, New York, 1979).CrossRefGoogle Scholar
11. Rehfuss, B.D., Liu, Di-Ja, Dinelli, B.M., Jagod, M.F., Ho, W.C., Crofton, M.W., and Oka, T., J. Chem. Phys. 89, 129 (1988).Google Scholar
12. Douglas, A.E., Can. J. Phys. 33, 801 (1955).Google Scholar
13. Bruna, P.J., Peyerimhoff, S.D., and Buenker, R.J., J. Chem. Phys. 72, 5437 (1980).Google Scholar
14. McLean, A.D., Liu, B., and Chandler, G.S., J. Chem. Phys. 80, 5130 (1984);Google Scholar
Lüthi, H.P., and Mclean, A.D., Chem. Phys. Lett. 135, 352 (1987).Google Scholar
15. Raghavachari, K., J. Chem. Phys. 84, 5672 (1986).Google Scholar
16. Bauschlicher, C.W., and Langhoff, S.R. J. Chem. Phys. 87, 2919 (1987).Google Scholar
17. Bruna, P.J., Dohmann, H., Anglada, J., Krumbach, V., Peyerimhoff, S.D., and Buenker, R.J., Journal of Molecular Structrure 93, 309 (1983).Google Scholar
18. Raghavachari, K., and Rohlfing, C.M., J. Chem. Phys. 1990, (to be published).Google Scholar
19. Nimlos, M.R., Harding, L.B., and Ellison, G.B., J. Chem. Phys. 87, 5116 (1987).Google Scholar
20. Metz, R.B., Weaver, A., Bradforth, S.E., Kitsopoulos, T.N., and Neumark, D.M., J. Phys. Chem. 94, 1377 (1990).CrossRefGoogle Scholar
21. Dietz, T.G., Duncan, M.A., Powers, D.E., and Smalley, R.E., J. Chem. Phys. 74, 6511 (1981);Google Scholar
Bondybey, V.E. and English, J.H. 74, 6978 (1981).Google Scholar
22. Kitsopoulos, T.N., Waller, I.M., Loeser, J.M., and Neumark, D.M., Chem. Phys. Lett. 159, 300 (1989).Google Scholar