Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-26T17:28:37.231Z Has data issue: false hasContentIssue false

Phase Stability of the L12 Compound and Microstructural Changes in Co-(W or Mo)-Ta Ternary Alloys

Published online by Cambridge University Press:  28 August 2018

Hibiki Chinen
Affiliation:
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-02 Aoba-yama, Sendai 980-8579, Japan
Toshihiro Omori
Affiliation:
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-02 Aoba-yama, Sendai 980-8579, Japan
Katsunari Oikawa
Affiliation:
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-02 Aoba-yama, Sendai 980-8579, Japan
Ikuo Ohnuma
Affiliation:
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-02 Aoba-yama, Sendai 980-8579, Japan
Ryosuke Kainuma
Affiliation:
Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Sendai 980-8577, Japan
Kiyohito Ishida
Affiliation:
Department of Materials Science, Graduate School of Engineering, Tohoku University, 6-6-02 Aoba-yama, Sendai 980-8579, Japan
Get access

Abstract

Microstructural investigations of Co-5W-2.5Ta (at.%) and Co-4Mo-4.5Ta (at.%) ternary alloys were conducted. Fine coherent precipitates were observed in these alloys annealed at 800°C, and the crystal structures of precipitates (γ’) and matrix (γ) phase were identified as the L12 and A1 structure, respectively, by transmission electron microscopy. Cellular precipitation with a γ+χ(D019) lamellar structure also proceeded at grain boundaries, and the alloys aged for a longer time only showed the γ+χ two-phase microstructure instead of the γ’ phase. With aging at around 800°C, the peak hardness of these alloys with a γ+γ’ two phase structure was about 580 Hv.

Type
Articles
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Sims, C. T., Stoloff, N. S. and Hagel, W. C., “Superalloys (2nd edition)”, John Wiley & Sons, New York (1987) pp. 135140.Google Scholar
2. Sato, J., Omori, T., Oikawa, K., Ohnuma, I., Kainuma, R. and Ishida, K., Science 312, 90 (2006).Google Scholar
3. Chinen, H., Sato, J., Omori, T., Oikawa, K., Ohnuma, I., Kainuma, R. and Ishida, K., Scripta Mater. 56, 141 (2007).Google Scholar
4. Blaise, J. M., Viatour, P. and Drapier, J. M., Cobalt 49, 192 (1970).Google Scholar
5. Viatour, P., Drapier, J. M., Coutsouradis, D. and Habraken, L., Cobalt 51, 67 (1971).Google Scholar
6. Viatour, P., Drapier, J. M. and Coutsouradis, D., Cobalt 3, 67 (1973).Google Scholar
7. Bradley, A. J. and Seager, G. C., J. Inst. Met. 64, 81 (1939).Google Scholar
8. Edwards, O. S., J. Inst. Met. 67, 67 (1941).Google Scholar
9. Omori, T., Sutou, Y., Oikawa, K., Kainuma, R. and Ishida, K., Mat. Sci. Eng. A 438-440, 1045 (2006).Google Scholar
10. Dutkiewicz, J. and Kostorz, G., Acta Metall. Mater. 38, 2283 (1990).Google Scholar
11. Dutkiewicz, J. and Kostorz, G., Mater. Sci. Eng. A 132, 267 (1991).Google Scholar
12. Dragsdorf, R. D. and Forgeng, W. D., Acta Cryst. 15, 531 (1962).Google Scholar
13. Korchynsky, M. and Fountain, R. W., Trans. A.I.M.E. 215, 1033 (1959).Google Scholar
14. Drapier, J. M., J. L. de Brouwer and Coutsouradis, D., Cobalt 27, 59 (1965).Google Scholar
15. Drapier, J. M. and Coutsouradis, D., Cobalt 39, 63 (1968).Google Scholar
16. Livingston, J. D. and Cahn, J. W., Acta Met. 22, 495 (1974).Google Scholar
17. Sato, J., Ph.D. thesis, Tohoku University, Japan, (2006).Google Scholar