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Phase Separation Behaviors Of Polyimide Blends

Published online by Cambridge University Press:  10 February 2011

C. H. Ryu
Affiliation:
Department of Industrial Chemistry, Hanyang University, Seoul 133-791 Korea, [email protected]
Y. C. Bae
Affiliation:
Department of Industrial Chemistry, Hanyang University, Seoul 133-791 Korea, [email protected]
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Abstract

We investigated phase behaviors of polyimide blends such as polyethermide(PEI)/polystyrene(PS), PEI/polyamideimide(PAI), PEI/polyethyleneoxide(PEO), and PAI/PEO systems. Our sample systems exhibited lower critical solution temperature(LCST) phase behaviors. In the PEI/PS system, phase transition occurred near or above the glass transition temperature(Tg) of PS and the critical temperature of the system increased with decreasing molecular weight of PS. For PEI/PAI and PEI/PEO systems, the critical temperature of PEI/PAI system is higher than that of PEI/PEO system. Phase transition temperatures of PAI/PEO systems appeared near or below the melting point of PEO.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1. Chen, S. T., Mat. Res. Soc. Symp. Proc. 381, p. 141(1995).Google Scholar
2. Odian, G., Principles of Polymerization, John Wiley & Sons, Inc, New York, p. 160(1991).Google Scholar
3. Lee, Y. K., Murarka, S. P., Jeng, S. P., and Auman, B., Mat. Res. Soc. Symp. Proc. 381, p. 31(1995).Google Scholar
4. Chen, H. L., Hwang, J. C., Chen, C. C., Wang, R. C., Fang, D. M., and Tsai, M. J., Polymer. 38, p. 2,747(1997).Google Scholar
5. Morales, A. R. and Bretas, R. E. S., Eur. Polym. J. 32, p. 349(1996).Google Scholar
6. Morales, A. R. and Bretas, R. E. S., Eur. Polym. J. 32, p. 365(1996).Google Scholar
7. Bae, Y. C., Shim, J. J., Soane, D. S., and Prausnitz, J. M., J. Appl. Polym. Sci. 47, p. 1,193(1993).Google Scholar
8. Bae, Y. C., J. Ind & Chem. 1, p. 18(1995).Google Scholar