Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-29T09:22:15.534Z Has data issue: false hasContentIssue false

Perovskite Catalysts: High-Surface Area Powders Synthesis, Monoliths Shaping and High-Temperature Applications

Published online by Cambridge University Press:  15 February 2011

Vladislav A. Sadykov
Affiliation:
Boreskov Institute of Catalysis ST RAN, pr. Lavrentieva, 5, Novosibirsk, 630090, Russia.
L.A. Isupova
Affiliation:
Boreskov Institute of Catalysis ST RAN, pr. Lavrentieva, 5, Novosibirsk, 630090, Russia.
S.F. Tikhov
Affiliation:
Boreskov Institute of Catalysis ST RAN, pr. Lavrentieva, 5, Novosibirsk, 630090, Russia.
O.N. Kimkhai.
Affiliation:
Boreskov Institute of Catalysis ST RAN, pr. Lavrentieva, 5, Novosibirsk, 630090, Russia.
Get access

Abstract

Monolith perovskite catalysts of honeycomb structure for high-temperature applications are elaborated. Problems of powdered perovskites synthesis by efficient plasmochemical and mechanochemical methods as related to real structure and reactivity of these compounds are discussed. Pilot testing in reactions of fuels combustion, ammonia oxidation, methane conversion and sulphur dioxide reduction proved high activity and stability of these catalysts.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Trimm, D.L., Appl. Catal. 7,249 (1983)Google Scholar
2. Tejuca, L.G., Fierro, J.L.G., Tascon, J.M.D., Adv. Catal. 36,237 (1989).Google Scholar
3. Avvakumov, E.G., Mechanical Methods of the Chemical Processes Activation, 2nd ed.(Nauka Publishers, Novosibirsk, 1986),305 p.Google Scholar
4. Parkhomenko, V.D., Tsybulev, P.N., Krasnokutskii, Yu.I., Technology of the Plasmochemical Processes, (Vyssha Shkhola Publishers, Kiev, 1992), 350 p.Google Scholar
5. Isupova, L.A., Sadykov, V.A., Solovyova, L.P., Andrianova, M.P.,Ivanov, V.P.,, Kryukova, G.N., Kolomiichuk, V.N.., Avvakumov, E.G., Pauli, I.A., Poluboyarov, V.A., Rozovskii, A.Ya. and Tretyakov, V.F., in Scientific Bases for the Preparation of Heterogeneous CatalystsVI, preprints. (Louvain-la-Neuve, Belgium. 1994).V.2. pp. 231239.Google Scholar
6. Tikhov, S.F., Sadykov, V.A., Pack, E.A., Kimkhai, O.N., Moroz, E.M., Ivanov, V.P., Kustova, G.N. and Alikina, G.M. in Heterogeneous Catalysis, edited by Petrov, L. and Andreev, A. (Proc. VII Int. Symp., Bourgas, Bulgaria, 1991, v.2), pp. 423428.Google Scholar
7. Pauli, I.A., Avvakumov, E.G., Isupova, L.I., Poluboyarov, V.A., Sadykov, V.A., Sib. Khim. Zhurn., 3, 133 (1992).Google Scholar
8. Isupova, L.A., Sadykov, V.A., Ivanov, V.P., Rar, A.A., Tsybulya, S.V., Andrianova, M.P., Kolomiichuk, V.N., Petrov, A.N., and Kononchuk, O.F., React. Kinet. Catal. Lett. 53, 223 (1994).Google Scholar
9. Razdobarov, V.A., PhD thesis, Boreskov Institute of Catalysis SD RAN, 1992.Google Scholar
10. Sadykov, V.A., Isupova, L.A., Tikhov, S.F., Kimkhai, O.N., Rosovskii, A.Ya., Tretyakov, V.F., Lunin, V.V., Petrov, A.N., Tsybulev, P.N., Voronin, P.N. in Proc. 4th Europ. East-West. Conference & Exibition on Materials and Processes (CRISH “Prometey”, St.-Petersburg, Russia, 1994), V.1.Google Scholar