Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-20T14:32:26.012Z Has data issue: false hasContentIssue false

PECVD Silicon Nitride for Damascene Applications

Published online by Cambridge University Press:  01 February 2011

Albert Lee
Affiliation:
Dielectric Systems & Modules Product Business Group, Applied Materials Inc., Santa Clara, CA 95054, U.S.A.
Nagarajan Rajagopalan
Affiliation:
Dielectric Systems & Modules Product Business Group, Applied Materials Inc., Santa Clara, CA 95054, U.S.A.
Maggie Le
Affiliation:
Dielectric Systems & Modules Product Business Group, Applied Materials Inc., Santa Clara, CA 95054, U.S.A.
Bok Heon Kim
Affiliation:
Dielectric Systems & Modules Product Business Group, Applied Materials Inc., Santa Clara, CA 95054, U.S.A.
Hichem M'Saad
Affiliation:
Dielectric Systems & Modules Product Business Group, Applied Materials Inc., Santa Clara, CA 95054, U.S.A.
Get access

Abstract

A Pecvd silicon nitride film, Damascene Nitride™, is deposited in a PECVD chamber with a hollow cathode faceplate using silane and ammonia as precursor gases. Various techniques (FTIR, RBS-HFS, SIMS, TDS and BTS) were used to characterize the structure, composition, density and wet etch rate of the film. FTIR analysis indicates that Damascene Nitride is very similar to a high density plasma (HDP) nitride film. HFS analysis shows the film's hydrogen content to be 13%,∼6% less than other PECVD nitride films, leading to a 20% improvement in etch selectivity to FSG. The film wet etch rate is 2 times slower than that of other PECVD nitrides, and the dielectric constant k was measured to be 6.8, which is lower compared to other PECVD nitrides and HDP CVD nitrides where k∼ 7.0 and 7.5, respectively. SIMS analysis shows that Cu diffusion is <250Å in the nitride, and low leakage current (10-10 A) is confirmed through BTS testing. The higher density of Damascene Nitride leads to higher etch selectivity and better Cu barrier properties, allowing a thinner nitride film to be used. Thinner nitride layers, in addition to the lower k of Damascene Nitride, leads to a 5-6% reduction in RC delay when Damascene Nitride is used with low k dielectric materials.

Type
Research Article
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. M'Saad, Hichem, Vellaikal, Manoj, Ma, Wen and Rossman, Kent, Advanced Metallization Conference 1999, Materials Research Society, 479 (1999).Google Scholar
2. Yota, J., Janani, M., Camilletti, L.E., Kar-Roy, A., Liu, Q.Z., Nguyen, C., Woo, M.D., Hander, J. and Cleemput, P. van, Proceedings of the International Interconnect Technology Conference 2000, 76 (2000).Google Scholar
3. Li, T., Kanicki, J., Fitzner, M. and Warren, W.L., AMLCDs '95 Second International Workshop on Active Matrix Liquid Crystal Displays, IEEE, 129 (1995).Google Scholar