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Oxygen Transport in the Sr2Fe3−x, CoxOy System

Published online by Cambridge University Press:  10 February 2011

B. Ma ,
U. Balachandran ,
B.J. Mitchell ,
J.W. Richardson Jr. ,
J.P. Hodges  and
J.D. Jorgensen
B. Ma
Affiliation:
Energy Technology Division, Argonne National Laboratory, Argonne, IL 60439
U. Balachandran
Affiliation:
Energy Technology Division, Argonne National Laboratory, Argonne, IL 60439
B.J. Mitchell
Affiliation:
Intense Pulsed Neutron Source, Argonne National Laboratory, Argonne, IL 60439
J.W. Richardson Jr.
Affiliation:
Intense Pulsed Neutron Source, Argonne National Laboratory, Argonne, IL 60439
J.P. Hodges
Affiliation:
Materials Science Division, Argonne National Laboratory, Argonne, IL 60439
J.D. Jorgensen
Affiliation:
Materials Science Division, Argonne National Laboratory, Argonne, IL 60439
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Abstract

The mixed-conducting Sr-Fe-Co oxide has potential use as a gas separation membrane. Its superior oxygen transport reveals the feasibility of using oxide membranes in large-scale oxygen separation. Sr2Fe3-xCoxOy (with x = 0.0, 0.3, 0.6, and 1.0) samples were made by solid state reaction. To understand the oxygen transport mechanism in this system, conductivity and thermogravimetry experiments were conducted at high temperature in various oxygen partial pressure environments. The oxygen diffusion coefficient was determined from the time relaxation transient behavior of the specimen after switching the surrounding atmosphere. Mobility of the charge carrier was derived from relative conductivity and weight changes. X-ray diffraction experiments were carried out on these samples to determine their crystal structures.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 569
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1. Takahashi, T. and Iwahara, H., Energy Convers., 11, 105 (1971).Google Scholar
2. Steele, B.C.H., Mater. Sci. Eng. B-Solid State M, 13, 79 (1992).Google Scholar
3. Minh, N.Q., J. Am. Ceram. Soc., 76, 563 (1993).Google Scholar
4. DiCosimo, R., Burrington, J.D., and Grasselli, R.K., J. Catal., 102, 377 (1992).Google Scholar
5. Kendall, K.R., Navas, C., Thomas, J.K., and Loye, H.-C., Solid State Ionics, 82, 215 (1995).Google Scholar
6. Balachandran, U., Dusek, T.J., Sweeney, S.M., Poeppel, R.B., Mieville, R.L., Maiya, P.S., Kleefisch, M.S., Pei, S., Kobylinski, T.P., Udovich, C.A., and Bose, A.C., Am. Ceram. Soc. Bull., 74, 71 (1995).Google Scholar
7. Ma, B., Park, J.-H., Segre, C.U., and Balachandran, U., Mater. Res. Soc. Symp. Proc., 393, 49 (1995).Google Scholar
8. Deng, H., Zhou, M., and Abeles, B., Solid State Ionics, 74, 75 (1994).Google Scholar
9. Pei, S., Kleefisch, M.S., Kobylinski, T.P., Faber, J., Udovich, C.A., Zhang-McCoy, V., Dabrowski, B., Balachandran, U., Mieville, R.L., and Poeppel, R.B., Catal. Lett., 30, 201 (1995).Google Scholar
10. Mazanec, T.J., Cable, T.L., and Frye, J.G. Jr., Solid State Ionics, 53–56, 111 (1992).Google Scholar
11. Cable, T.L., European Patent EP 0438 902 A2, July 31 (1991).Google Scholar
12. Teraoka, Y., Nobunaga, T., and Yamazoe, N., Chem. Lett., 1988, 503 (1988).Google Scholar
13. Anderson, M.T., Vaughey, J.T., and Poeppelmeier, K.R., Chem. Mater., 5, 151 (1993).Google Scholar
14. Ma, B., Balachandran, U., Park, J.-H., and Segre, C.U., J. Electrochem. Soc., 143, 1736 (1996).Google Scholar
15. Ma, B., Hodges, J.P., Jorgensen, J.D., Miller, D.J., Richardson, J.W. Jr., and Balachandran, U., to be published in J. Solid State Chem., (1999).Google Scholar
16. Rietveld, H.M., J. Appl. Cryst., 2, 65 (1969).Google Scholar
17. Ma, B., Balachandran, U., Park, J.-H., and Segre, C.U., Solid State Ionics, 83, 65 (1996).Google Scholar
18. Ma, B., Balachandran, U., Solid State Ionics, 100, 53 (1997).Google Scholar
19. Yoshiasa, A., Ueno, K., Kanamaru, F., and Horiuchi, H., Mater. Res. Bull., 21, 175 (1986).Google Scholar