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Oxygen Ion Conductivity in a New Class of Layered Bismuth Oxide Compounds

Published online by Cambridge University Press:  25 February 2011

Julie K. Thomas
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, MA 02139.
Mairin E. Anderson
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, MA 02139.
Wendy E. Krause
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, MA 02139.
Hansconrad Zur Loye
Affiliation:
Massachusetts Institute of Technology, Department of Chemistry, Cambridge, MA 02139.
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Abstract

Compounds that consist of intergrowths between the Aurivillius phase Bi4Ti3O12 and brownmillerite-like slabs of BaMO2.5were synthesized and their oxygen ion conductivities investigated. Both BaBi4Ti3ScO14.5 and BaBi4Ti3InO14.5 display a discontinuity in their Arrhenius plots that appears to be caused by an oxygen vacancy order-disorder transition. Conductivity data for two Aurivillius phases BaBi4Ti4O15 and BaBi2Nb2O9 are included for comparison.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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References

1. Dell, R. M. & Hooper, A. in “Solid Electrolytes,” eds. Hagenmoller, P. & van Gool, W. (Academic Press, New York, 1978) p. 291312.Google Scholar
2. Hagenmuller, P. in “Superionic Solids and Solid Electrolytes,” eds. Laskar, A. L. & Chandra, S. (Academic Press, New York, 1989) p. 679704.Google Scholar
3. Riess, I. in “Science and Technology of Fast Ion Conductors,” eds. Tuller, H. L. & Balkanski, M. (Plenum Press, New York, 1987) p. 2350.Google Scholar
4. Takahashi, T. in “Superionic Solids and Solid Electrolytes,” eds. Laskar, A. L. & Chandra, S. (Academic Press, New York, 1989) p. 141.Google Scholar
5. Burggraaf, A. J., Van Dijk, M. P., Verkerk, M. J. & de Vries, K. J.Structure and Conductivity of Some Pyrochlore and Fluorite TypeSolid Solutions” (Elsevier Scientific Publishing Company, Veldhoven, The Netherlands, 1982) p. 185188.Google Scholar
6. Faktor, J. D., Kilner, J. A. & Steele, B.C.H. in “Solid State Chemistry 1982, Proceedings of the Second European Conference, Veldhoven, The Netherlands, 7-9 June 1982,” eds. Metselaar, R., Heijligers, H. J. M. & Schoonman, J. (Eslevier Scientific Publishing Company, Amsterdam, 1983) p. 207210.Google Scholar
7. van Dijk, M. P., Burggraaf, A.J., Cormack, A. N. & Catlow, C. R. A. Solid State Ionics 17, 159167 (1985).Google Scholar
8. Kilner, J. A. & Brook, R. J. Solid State Ionics 6, 237252 (1982).Google Scholar
9. Catlow, C. R. A. in “Superionic Solids and Solid Electrolytes,” eds. Laskar, A. L. & Chandra, S. (Academic Press, New York, 1989) p. 339379.Google Scholar
10. Nowick, A. S. Comments Solid State Phys. 9, 8591 (1979).Google Scholar
11. Worrell, W. L. in “Solid Electrolytes,” eds. Geller, S. (Springer-Verlag, Berlin, 1977) p. 143168.Google Scholar
12. Kilner, J. A. & Waters, C. D. Solid State Ionics 6, 253259 (1982).Google Scholar
13. Subbarao, E. C. & , Ramakrichnan. in “Fast Ion Transport in Solids,” eds. Mundy, Vashishta & Shenoy, (Elsevier, North Holland, 1979) p. 653656.Google Scholar
14. Subbarao, E. C. J. Am. Ceram. Soc. 45, 166169 (1962).Google Scholar
15. Wolfe, R. W., Newnham, R. E. J. Electrochem. Soc.: Solid State Science 116, 832835 (1969).Google Scholar
16. Newnham, R. E., Wolfe, R. W., Dorrian, J. F. Mat. Res. Bull. 6, 10291040 (1971).Google Scholar
17. Berggren, J. Acta Chem. Scand. 25, 36163624 (1971).Google Scholar
18. Shin, S., Yonemura, M. & Ikawa, H. Mat. Res. Bull. 13, 10171021 (1978).Google Scholar
19. Mader, K. & , Müller-Buschbaum, H. J. Less-Common Met. 157, 7176 (1990).Google Scholar
20. Grenier, J.-C., Darriet, J., Pouchard, M. & Hagenmuller, P. Mat. Res. Bull. 11, 12191226 (1976).Google Scholar
21. Battle, P. D., Gibb, T. C. & Nixon, S. J. Solid State Chem. 79, 7585 (1989).Google Scholar
22. Poeppelmeier, K. R., Leonowicz, M. E. & Longo, J. M. J. Solid State Chem. 44, 8998 (1982).Google Scholar
23. Goodenough, J. B., Ruiz-Diaz, J. E. & Zhen, Y. S. Solid State Ionics 44, 2131 (1990).Google Scholar