Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-29T11:06:26.321Z Has data issue: false hasContentIssue false

Oxidation and Protection of Ti3AL-Based Intermetallic Alloys

Published online by Cambridge University Press:  01 January 1992

Douglas W. Mckee*
Affiliation:
General Electric Corporate Research and Development, P.O. Box 8, Schenectady, New York 12301.
Get access

Abstract

Titanium aluminides containing 20-30 atom percent Al can suffer from severe subsurface embrittlement (alpha-case) when exposed to air at elevated temperatures for extended periods. For example.the alloys Ti-24Al-12.5Nb-l.5Mo and Ti-24Al-8Nb-2Mo-2Ta (based on the Ti3Al alpha-2 intermetallic compound) embrittle to a depth of about 80 microns during 1000 hours exposure to air at 815°C (1500°F), resulting in major reductions in tensile properties. Plasma-sprayed coatings of the MCrAlY and MCr types deposited over a thin diffusion barrier of chromium or tungsten, have been found effective in protecting these alloys against oxidation and embrittlement at this temperatures.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Lipsett, H.A., MRS Symposium Proc., 39, 351 (1985).Google Scholar
2. Gigliotti, M.F.X. and Marquardt, B.J., U.S.Patent 4,788,035, 1988.Google Scholar
3. Pickens, J.W. and Watson, G.K., paper at 14th. Conf.,on Metal Matrix, Carbon, and Ceramic Composites, Cocoa Beach, FL, Jan. 1990.Google Scholar
4. Liu, Z. and Welsch, G., Met. Trans. 19A, 1121 (1988).Google Scholar
5. Balsone, S. in “Oxidation of High Temperature Intermetallics” (Grobstein, T. and Doychak, J., Eds.) p.219, TMS, 1988.Google Scholar
6. McKee, D.W. and Luthra, K.L., Surf. Coatings Tech., to be published.Google Scholar
7. McKee, D.W., paper at AeroMat '92 Conference, Anaheim, CA, May 1992.Google Scholar
8. Barbuto, A. and McKee, D.W., paper at IMS Conf., Monterey, CA, July 1991.Google Scholar