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The osmosis-induced swelling and NaNO3 leaching of radioactive and artificially aged Eurobitum bituminized waste

Published online by Cambridge University Press:  23 March 2012

An Mariën ,
Elie Valcke ,
Nele Bleyen  and
Steven Smets
An Mariën
Affiliation:
W&D Expert Group, SCK•CEN, Boeretang 200, 2400 Mol, Belgium.
Elie Valcke
Affiliation:
W&D Expert Group, SCK•CEN, Boeretang 200, 2400 Mol, Belgium.
Nele Bleyen
Affiliation:
W&D Expert Group, SCK•CEN, Boeretang 200, 2400 Mol, Belgium.
Steven Smets
Affiliation:
W&D Expert Group, SCK•CEN, Boeretang 200, 2400 Mol, Belgium.
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Abstract

The behavior of Eurobitum bituminized radioactive waste under geological disposal conditions is studied in water uptake tests at the Belgian Nuclear Research Centre SCK•CEN to assess the feasibility of geological disposal for the long-term management of this waste. The hydro-mechanical behavior of this waste is affected by the continuous evolution of the rheological properties of bitumen due to radio-oxidation (i.e. ageing).

The effect of the bitumen ageing degree on the kinetics of the water uptake, swelling and NaNO3 leaching is investigated in water uptake tests with ∼30 years old radioactive samples and inactive samples that were artificially aged. The first results of swelling and NaNO3 leaching of (i) radioactive samples that have been hydrated for more than 2 years at a constant total stress of 2.2 MPa, and (ii) a thermally aged sample that has been hydrated for ∼1.5 years under nearly zero effective stress conditions, revealed lower swelling and higher leach rates for these samples compared to non-aged samples. The effect of ageing on the osmotic efficiency of bitumen as a semi-permeable membrane is less pronounced when swelling of the samples is limited, and changes in time, probably because of the formation of low porosity layers, which seems to mask the difference in bitumen membrane efficiency of aged and non-aged bituminized waste.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1475: Symposium NW – Scientific Basis for Nuclear Waste Management XXXV , 2012 , imrc11-1475-nw35-o12
Copyright
Copyright © Materials Research Society 2012

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References

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