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Organic/Inorganic Molecular Hybrid Materials From Cubic Silsesquioxanes

Published online by Cambridge University Press:  10 February 2011

R. M. Laine ,
M. Asuncion ,
S. Baliat ,
N. L. Dias Filho ,
J. Harcup ,
A. C. Sutorik ,
L. Viculis ,
A. F. Yee ,
C. Zhang  and
Q. Zhu
R. M. Laine
Affiliation:
Depts. of Materials Science and Eng., Chemistry and the Macromolecular Science and Eng. Center, University of Michigan, Ann Arbor, MI 48109–2136, U.S.A
M. Asuncion
Affiliation:
Depts. of Materials Science and Eng., Chemistry and the Macromolecular Science and Eng. Center, University of Michigan, Ann Arbor, MI 48109–2136, U.S.A
S. Baliat
Affiliation:
Tal Materials, Inc., 912 N. Main St., Ann Arbor, MI 48104
N. L. Dias Filho
Affiliation:
Depts. of Materials Science and Eng., Chemistry and the Macromolecular Science and Eng. Center, University of Michigan, Ann Arbor, MI 48109–2136, U.S.A
J. Harcup
Affiliation:
Depts. of Materials Science and Eng., Chemistry and the Macromolecular Science and Eng. Center, University of Michigan, Ann Arbor, MI 48109–2136, U.S.A
A. C. Sutorik
Affiliation:
Tal Materials, Inc., 912 N. Main St., Ann Arbor, MI 48104
L. Viculis
Affiliation:
Depts. of Materials Science and Eng., Chemistry and the Macromolecular Science and Eng. Center, University of Michigan, Ann Arbor, MI 48109–2136, U.S.A
A. F. Yee
Affiliation:
Depts. of Materials Science and Eng., Chemistry and the Macromolecular Science and Eng. Center, University of Michigan, Ann Arbor, MI 48109–2136, U.S.A
C. Zhang
Affiliation:
Depts. of Materials Science and Eng., Chemistry and the Macromolecular Science and Eng. Center, University of Michigan, Ann Arbor, MI 48109–2136, U.S.A
Q. Zhu
Affiliation:
Depts. of Materials Science and Eng., Chemistry and the Macromolecular Science and Eng. Center, University of Michigan, Ann Arbor, MI 48109–2136, U.S.A
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Abstract

Octafunctionalized silsesquioxanes [(RsiO1.5)8, cubes] offer potential as rigid, hard nanoplatforms to which a variety of organofunctional groups can be appended. Crosslinking these groups leads to novel organic/inorganic nanocomposites that consist primarily of interfacial interactions. These materials can be 100% interphase. We present efforts to develop nanocomposite materials that consist of both continuous and discontinuous organic/inorganic phases. We then discuss methods of probing the properties of these materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 3
Copyright
Copyright © Materials Research Society 1999

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References

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