Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-20T03:55:43.179Z Has data issue: false hasContentIssue false

Novel Silica-Sol Mediated Synthesis of Nanoporous Carbons

Published online by Cambridge University Press:  10 February 2011

Taeghwan Hyeon
Affiliation:
School of Chemical Engineering and Institute of Chemical Processes, Seoul National University, Seoul 151-742, Korea, e-mail: [email protected]
Sangjin Han
Affiliation:
School of Chemical Engineering and Institute of Chemical Processes, Seoul National University, Seoul 151-742, Korea, e-mail: [email protected]
Kwonnam Sohn
Affiliation:
School of Chemical Engineering and Institute of Chemical Processes, Seoul National University, Seoul 151-742, Korea, e-mail: [email protected]
Get access

Abstract

New preparative methods for the synthesis of nanoporous carbons using silica particles as templates will be presented. Gellation of resorcinol and formaldehyde in the presence of silica sol particles generated RF gel-silica nanocomposite. Carbonization followed by HF etching of silica templates generated nanoporous carbons with pore size ranging 10 ∼ 100 nm. When silica particles stabilized with surfactant were used as templates, uniform ∼ 10 nm pore-sized carbons have been formed. These nanoporous carbons exhibited excellent adsorption capacity for dyes.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Rodriguez-Reinoso, F., in Introduction to Carbon Technology, ed. Marsh, H., Heintz, E. A., and Rodriguez-Reinoso, F., Universidad de Alicante, Secretariado de Publications, Alicante, 1997, p. 35.Google Scholar
2. Pekala, R. W., J. Mater. Sci. 24, 3221 (1989).Google Scholar
3. Kresege, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., Beck, J. S., Nature 359, 710 (1992).Google Scholar
4. Ying, J. Y., Mehnert, C. P., Wong, M. S., Angew. Chem. Int. Ed. Engl. 38, 57 (1999).Google Scholar
5. Imhof, A. and Pine, D. J., Nature 389, 948 (1997); T. Holland, C. F. Blandford and A. Stein, Science 281, 538 (1998); J. E. G. J. Wijnhoven, W. L. Vos, Science 281, 802 (1998).Google Scholar
6. Han, S. and Hyeon, T., Carbon 37, 1645 (1999).Google Scholar
7. Han, S. and Hyeon, T., Chem. Comm. 1955 (1999).Google Scholar