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A Novel Photosensitive Polyimide

Published online by Cambridge University Press:  25 February 2011

Takashi Hirano
Affiliation:
SUMITOMO BAKELITE CO., LTD. Fundamental Research Laboratory 495 Akiba-cho, Totsuka-ku, Yokohama, Kanagawa 245 Japan
Nobuyuki Sashida
Affiliation:
SUMITOMO BAKELITE CO., LTD. Fundamental Research Laboratory 495 Akiba-cho, Totsuka-ku, Yokohama, Kanagawa 245 Japan
Toshiro Takeda
Affiliation:
SUMITOMO BAKELITE CO., LTD. Fundamental Research Laboratory 495 Akiba-cho, Totsuka-ku, Yokohama, Kanagawa 245 Japan
Akira Tokoh
Affiliation:
SUMITOMO BAKELITE CO., LTD. Fundamental Research Laboratory 495 Akiba-cho, Totsuka-ku, Yokohama, Kanagawa 245 Japan
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Abstract

We developed a novel negative photosensitive polyimide composition for microelectronics. It was prepared by the synthesis of polyamic acid precursor in N, N-dimethly acryl amide. The solution properties, processing conditions and film properties are compared with two conventional, ester and ion type photosensitive polyimides.

The novel composition has higher sensitivity than the other two types because the density of the photoreactive groups is much higher. And it provides wider patterning process range, better adhesion and lower final curing temperature.

We also examined the effect between three types of polyimides and epoxy molding compounds on the reliability of ICs after moisture/solder reflow process. The novel photosensitive composition has good adhesion to metals, inoranic layers and molding compound and improves the reliability of ICs by supressing the interfacial delamination.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

REFERENCES

(1) Ahne, H. and Rubner, R., “A simple way to producing industrial polyimide patterns”, Simens Forsch.-u Entwicki.-Ber., vol. 10, pp. 112, 1987 Google Scholar
(2) Yoda, N. and , Hiramoto, “New photosensitive high temperature polymers for electronics applications”, J. Macromil Sci.-Chem., vol. A21, pp. 1641, 1984 Google Scholar
(3) Nakano, T.. Proc. 2nd Inter. Conf. Polyimides, Ellenville, New York, pp. 163, 1985 Google Scholar
(4) Pfeifer, J., Rohde, O., Proc. 2nd Inter. Conf. Polyimides, Ellenville, New York, pp. 130, 1985 Google Scholar
(5) , Kojima et al. , “Photosensitive Polyimide for IC Device” Preprints of 39th Electronic Components Conf. 1989 Google Scholar
(6) Ahne, H. and Kuhn, E., Jpn Koukai Tokkyo Kouhoh, No. 60–228537, 1985 Google Scholar
(7) Rohde, O., Riediker, M., Schuffner, A., “Recent advances in photoimagable polyimides” SPIE vol. 539, Advances in Resist Technology and Processing II, pp. 175, 1985 Google Scholar
(8) Kojima, Mitsumasa et al. , “Photosensitive polyimide for IC devices”. Proc. 39th Electronic Components Conf., pp. 920, 1989 Google Scholar
(9) Naito, N., Tsunoda, N. andWada, T., “Development characteristics of photoreactive polyimide”, Denshi Tsuushin Gattsukai Ronbunshi, vol. J68, pp. 8, 1988 Google Scholar
(10) , Hiramoto, “Photosensitive polyimide”, Netsukoukaseijushi, vol. 9, pp. 8, 1988 Google Scholar
(11) Sashida, N., Hirano, T. and Tokoh, A., (“Photosensitive polyimides with excellent adhesive property for integrated circuit devices”, Proc. 39th Electronic Components Conf., pp. 167, 1989 Google Scholar
(12) Atalar, A. et al. , “Acoustic microscopy with microwave frequencies”, Ann. Rev. Mater. Sci. pp. 255, 1979 Google Scholar