Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-06T07:20:43.580Z Has data issue: false hasContentIssue false
  • English
  • Français

New Systems Related to CdS Nanoparticles in Sol-Gel Matrices

Published online by Cambridge University Press:  15 February 2011

T. Gacoin ,
L. Malier ,
G. Counio ,
S. Esnouf ,
J. P. Boilot ,
L. Audinet ,
C. Ricolleau  and
M. Gandais
T. Gacoin
Affiliation:
Laboratoire PMC, CNRS URA 1254, Ecole Polytechnique, 91128 Palaiseau Cedex, France.tga@pmcsunl. Polytechnique.fr
L. Malier
Affiliation:
Laboratoire PMC, CNRS URA 1254, Ecole Polytechnique, 91128 Palaiseau Cedex, France.tga@pmcsunl. Polytechnique.fr
G. Counio
Affiliation:
Laboratoire PMC, CNRS URA 1254, Ecole Polytechnique, 91128 Palaiseau Cedex, France.tga@pmcsunl. Polytechnique.fr
S. Esnouf
Affiliation:
Laboratoire PMC, CNRS URA 1254, Ecole Polytechnique, 91128 Palaiseau Cedex, France.tga@pmcsunl. Polytechnique.fr
J. P. Boilot
Affiliation:
Laboratoire PMC, CNRS URA 1254, Ecole Polytechnique, 91128 Palaiseau Cedex, France.tga@pmcsunl. Polytechnique.fr
L. Audinet
Affiliation:
Laboratoire de Minéralogie-Cristallographie, Universités Paris VI et Paris VII, CNRS URA 009, 4 Place Jussieu, 75252 Paris Cedex 05, France.
C. Ricolleau
Affiliation:
Laboratoire de Minéralogie-Cristallographie, Universités Paris VI et Paris VII, CNRS URA 009, 4 Place Jussieu, 75252 Paris Cedex 05, France.
M. Gandais
Affiliation:
Laboratoire de Minéralogie-Cristallographie, Universités Paris VI et Paris VII, CNRS URA 009, 4 Place Jussieu, 75252 Paris Cedex 05, France.
Get access

Abstract

A process for the synthesis of CdS nanoparticles embedded in hybrid organic/inorganic silica matrices has been developed, based both on colloid and sol-gel chemistry. The large possibilities offered by these techniques allow the study of the influence of various parameters on the luminescence properties of the nanoparticles. Two directions were investigated: first, we characterized the surface of the nanoparticles complexed with an organic thiol using NMR spectroscopy. Then, we synthesized new systems to study the influence of chemical modifications, such as the composition of the aggregates (CdS:Mn), the surface (CdS/ZnS core/shell nanostructures) and the interface between the aggregate and the gel matrix.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 643
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Gacoin, T., Train, C., Chaput, F., Boilot, J.P., Aubert, P., Gandais, M., Wang, Y. and Lecomte, A. in Sol-Gel Optics II, edited by the SPIE (SPIE Proc. 1758, San-Diego, CA, 1992) pp.565.Google Scholar
2. Schmidt, H., Sol-Gel Optics, edited by Klein, L. (Kluwer Academic Publishers 1994), 20, 451 M. Nogami, ibid., 15, 329.Google Scholar
3. Wang, Y., Herron, N., Phys. Rev. B 42 (11), 7253 (1990).Google Scholar
4. Steigerwald, M.L., Alivisatos, A.P., Gibson, J.M., Harris, T.D., Kortan, R., Muller, A.J., Thayer, A.M., Duncan, T.M., Douglas, D.C., Brus, L.E., J. Am. Chem. Soc. 110, 3046 (1988).Google Scholar
5. Lee, G.S., Fisher, K.J., Vassallo, A.M., Hanna, J.V., Dance, I.G., Inorg. Chem. 32, 66 (1993).Google Scholar
6. Counio, G., Esnouf, S., Boilot, J.P. and Gacoin, T., to be published.Google Scholar
7. Chamarro, M.A., Voliotis, V., Grousson, R., Lavallard, P., Gacoin, T., Counio, G., Boilot, J.P., Cases, R., accepted in J. Cryst. Growth (1996).Google Scholar
8. Bhargava, R.N., Gallager, D., Hong, X., Nurmikko, A., Phys. Rev. Lett. 72 (1994) 416.Google Scholar
9. Gandais, M., Audinet, L., Ricolleau, C., Gacoin, T., Boilot, J.P., accepted in J. Cryst. Growth (1996)Google Scholar