Hostname: page-component-5cf477f64f-fcbfl Total loading time: 0 Render date: 2025-04-08T11:00:34.880Z Has data issue: false hasContentIssue false
  • English
  • Français

A New Polymer-Based Hydrogen Getter

Published online by Cambridge University Press:  28 February 2011

Laura R. Gilliom
Laura R. Gilliom*
Affiliation:
Sandia National Laboratories, Division 1811, Albuquerque, NM 87185-5800
Get access

Abstract

Styrene-butadiene triblock copolymer PS-PB-PS was hydrogenated in the bulk using the Crabtree catalyst [Ir(COD)(py)(tcyp)]PF6 (COD = 1,5-cyclooctadiene, py = pyridene, tcyp = tricyclohexylphosphine). Since this polymer/catalyst mixture reacts rapidly with hydrogen at ambient temperature and low hydrogen pressures, it should act as an effective hydrogen getter.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 111: Symposium O – Microstructure and Properties of Catalysts , 1987 , 365
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

References and Notes

1. Giorgi, T. A., Ferrario, B., Storey, B., J. Vac. Sci. Technol., A, 3 (2), 417 (1985).Google Scholar
2. Courtney, R. L. and Harrah, L. A., J. Mater. Sci. 12, 175 (1977). D. R. Anderson, R. L. Courtney, L. A. Harrah, U. S. Patent No. 3 896 042 (22 July 1975) and U. S. Patent No. 3 963 826 (15 July 1976).Google Scholar
3. Smith, H. M., personal communication.Google Scholar
4. Gilliom, L. R., presented at the 1987 ACS Spring Meeting, Denver, CO, 1987 (manuscript in preparation).Google Scholar
5. The catalyst was prepared by literature methods: Crabtree, R. H., Morehouse, S. M., Quirk, J. M., Inorg. Synth. 24, 173 (1986).Google Scholar
6. Crabtree, R., Accts. Chem. Res. 12, 331 (1979) and references therein.CrossRefGoogle Scholar
7. Recent evaluation of samples containing 1 wt % catalyst indicate that even faster initial hydrogen uptake rates can be obtained at lower loadings. The observed capacity, however, is reduced as compared to the 9 wt % material.Google Scholar