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New Method for the Determination of Diffusion Constants from Partially Narrowed Nmr Lines*

Published online by Cambridge University Press:  15 February 2011

D. Wolf
D. Wolf*
Affiliation:
Materials Science Division, Argonne National Laboratory, Argonne, IL 60439
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Abstract

The effect of atomic and molecular motions on the NMR free-induction decay (FID) and lineshape is investigated theoretically in the intermediate temperature range in which the NMR line is only partially narrowed. It is shown that the FID may be decomposed into the weighted sum of a rigid-lattice (background) contribution and an exponentially decaying part containing all the information on the diffusive or reorientational motions in the crystal in terms of the spin-spin relaxation time T2.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 3: Symposium – Nuclear and Electron Resonance Spectroscopies Applied to Materials Science , 1980 , 529
Copyright
Copyright © Materials Research Society 1981

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Footnotes

*

Work supported by the U.S. Department of Energy.

References

REFERENCES

1. Wolf, D., Spin Temperature and Nuclear Spin Relaxation in Matter, Clarendon Press, Oxford, 1979.Google Scholar
2. Abragam, A., Principles of Nuclear Magnetism, Clarendon Press, Oxford, 1962, Chapter VIII.Google Scholar
3. Lado, F., Memory, J. P. and Parker, G. W., Phys. Rev. B 7, 2910 (1973).Google Scholar
4. Deutch, J. N. and Oppenheim, I., Adv. Magn. Res. 3, 43 (1968).Google Scholar
5. Redfield, A. G., IBM J. Res. Develop. 1, 19 (1957).Google Scholar
6. Redfield, A. G., Adv. Magn. Res. 1, 1 (1965).Google Scholar
7. Slichter, C. P., Principles of Magnetic Resonance, Harper and Row, New York, 1963, Chapter 5.Google Scholar
8. Kubo, R. and Tomita, K., J. Phys. Soc. Japan 9, 888 (1954).CrossRefGoogle Scholar
9. Abragam, A., Principles of Nuclear Magnetism, Clarendon Press, Oxford, 1962, Chapters IV and X.Google Scholar