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New Layered Perovskite Vanadium Oxide with Negative Magnetization

Published online by Cambridge University Press:  26 February 2011

Noburu Fukushima
Affiliation:
Advanced Research Laboratory. Research & Development Center TOSHIBA CORPORATION 1, Komukai Toshiba-cho, Saiwai-ku, Kawasaki, 210 JAPAN
Shiro Takeno
Affiliation:
Advanced Research Laboratory. Research & Development Center TOSHIBA CORPORATION 1, Komukai Toshiba-cho, Saiwai-ku, Kawasaki, 210 JAPAN
Shigenori Tanaka
Affiliation:
Advanced Research Laboratory. Research & Development Center TOSHIBA CORPORATION 1, Komukai Toshiba-cho, Saiwai-ku, Kawasaki, 210 JAPAN
Ken Ando
Affiliation:
Advanced Research Laboratory. Research & Development Center TOSHIBA CORPORATION 1, Komukai Toshiba-cho, Saiwai-ku, Kawasaki, 210 JAPAN
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Abstract

A new layered perovskite vanadium oxide Sr4V3O8-d was synthesized and its crystal structure and magnetic properties were studied. Sr4V3O8-d has a novel crystal structure, containing a V-0 octahedron and a two-fold V-0 fence in a unit cell. It exhibits negative magnetization below 30 K. when cooled in a magnetic field. This peculiar magnetism is attributed to N-type parasitic ferrimagnetism.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

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