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Neutron Scattering Studies of Glassy Solid-State Lithium Ion Based Electrolytes

Published online by Cambridge University Press:  06 September 2013

Tom Heitmann ,
Syed Ali S. Zaidi ,
Leo Zella ,
Munesh Rathore ,
Anshuman Dalvi  and
Saibal Mitra
Tom Heitmann
Affiliation:
The Missouri Research Reactor Center, University of Missouri, Columbia, MO 65211, U.S.A.
Syed Ali S. Zaidi
Affiliation:
Department of Physics, Astronomy, and Materials Science, Missouri State University, Springfield, MO 65897, U.S.A.
Leo Zella
Affiliation:
Department of Physics, New Mexico State University, Las Cruces, NM 88003, U.S.A.
Munesh Rathore
Affiliation:
Department of Physics, Birla Institute of Technology and Science, Pilani, India.
Anshuman Dalvi
Affiliation:
Department of Physics, Birla Institute of Technology and Science, Pilani, India.
Saibal Mitra*
Affiliation:
Department of Physics, Astronomy, and Materials Science, Missouri State University, Springfield, MO 65897, U.S.A.
*
*corresponding author: [email protected]
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Abstract

We present neutron diffraction results on superionic materials that are good candidates for use as solid-state electrolytes in next generation Li+ ion batteries. Lithium ion conducting glasses of the compositions xLi2SO4-(1-x) [0.5Li2O-0.5(2NH4H2PO2)] ; x=0 and 0.1 were synthesized by conventional melt-quenching. The transparent homogeneous glassy flakes were thus obtained and used for the characterization. The materials are glassy in nature and composed of a complex network of the following sub-units: Li2O, Li2SO4, and 2NH4H2PO2. This disordered structure is integral to its function in that it promotes Li+ ion conduction while suppressing electronic conduction, the necessary qualities of a good Li+ electrolyte. We used neutron diffraction to study the formation of crystallites upon heating of the material above 400°C. The crystallite formation is understood to be detrimental to the Li+ ion mobility and, hence, is identified with a diminished performance in devices that require heating in their fabrication processs. Here, we report the changes in the material, as observed by neutron diffraction, as a function of annealing temperature and temperature history.

Keywords

neutron scatteringLienergy storage
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1540: Symposium E – Materials and Integration Challenges for Energy Generation and Storage in Mobile Electronic Devices , 2013 , mrss13-1540-e03-05
Copyright
Copyright © Materials Research Society 2013 

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References

REFERENCES

Nazri, G.-A. and Pistoia, G., Lithium Batteries: Science and Technology; Kluwer Academic/Plenum: Boston, MA, 2004.Google Scholar
Tuller, H. L., Button, D. P., and Uhlmann, D. R., J. Non-Cryst Solids 40, 93 (1980).CrossRefGoogle Scholar
Souquet, J. L., Ann. Rev. Mater. Sci. 11, 211 (1981).CrossRefGoogle Scholar
Boolchand, P. and Bresser, W. J., Nature 410, 1070 (2001).CrossRefGoogle Scholar
Tatsumisago, M., Solid State Ionics 175, 13 (2004).CrossRefGoogle Scholar
Quartarone, E. and Mustarelli, P., Chem. Soc. Rev. 40, 2525 (2011).CrossRefGoogle Scholar
Machida, N., Yamamoto, H., Asano, S., and Shigematsu, T., Solid State Ionics 176, 473 (2005).CrossRefGoogle Scholar
Tatsumisago, M., Shinkuma, Y., and Minami, T., Nature 354, 217 (1991).CrossRefGoogle Scholar
Gupta, N. and Dalvi, A., Solid State Ionics 225, 363 (2012).CrossRefGoogle Scholar
Hirai, K., Tatsumisago, M., and Minami, T., Solid State Ionics 78, 269 (1995).CrossRefGoogle Scholar
Yelon, W.B., Berliner, R., and Popovici, M., Physica B 241-243, 237 (1998).Google Scholar
Thompson, C.W., Mildner, D.F.R., Mehregany, M., Sudol, J., Berliner, R., and Yelon, W.B., Journal of Applied Crystallography 17, 385 (1984).CrossRefGoogle Scholar
Popovici, M. and Yelon, W., Journal of Neutron Research 5, 227 (1997).CrossRefGoogle Scholar
Naumova, M.I., Kuratieva, N.V., Naumov, D. Yu., and Podberezskaya, N.V., Journal of Structural Chemistry 45, 465 (2004).CrossRefGoogle Scholar
Nord, A.G., Acta Crystallographica B32, 982 (1976).CrossRefGoogle Scholar
Rathore, M. and Dalvi, A., Solid State Ionics 239, 50 (2013).CrossRefGoogle Scholar