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Neutron Scattering from Charged Polymer Latices

Published online by Cambridge University Press:  26 February 2011

John B. Hayter
John B. Hayter*
Affiliation:
Solid State Division, Oak Ridge National Laboratory, P.O. Box X, Oak Ridge, TN 37831-6031.
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Abstract

Aqueous suspensions of charged polymer latex particles exhibit several forms of ordered structure, the particular form depending on the size, number density and charge of the latex particles, and on the ionic strength of the aqueous medium. At low ionic strength, the inter-particle potential may become sufficiently long-ranged to generate crystalline order, which usually shows bcc symmetry at low density and becomes fcc above about 3% volume fraction of latex in the system. As the ionic strength increases, the crystalline structure melts, and ordered liquid structures develop. Light scattering may be used to study these structures at low density, but at higher density, where the opacity of the suspensions renders optical techniques intractable, neutron scattering must be used.

This paper will review some of the recent small-angle neutron scattering experiments on polymer latex suspensions, in the light of new theoretical methods which permit in situ analysis of the particle size and charge. The discussion will also encompass new experimental methods for studying latex structures under dynamic shear conditions.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 79: Symposium F – Scattering, Deformation and Fracture in Polymers , 1986 , 241
Copyright
Copyright © Materials Research Society 1987

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References

1. Ottewill, R.H., in Emulsion Polymerization, edited by Pinrma, I. (Academic Press, New York, 1982).Google Scholar
2. Verwey, E.J.W. and Overbeek, J.Th. G., Theory of the Stability of Lyophobic Colloids (Elsevier, Amsterdam, 1948).Google Scholar
3. Egelstaff, P.A., An Introduction to the Liquid State (Academic Press, New York, 1967).Google Scholar
4. Hayter, J.B. and Penfold, J., J. Chem. Soc. Faraday Trans. I, 77, 1851 (1981); Mol. Phys. 42, 109 (1981).Google Scholar
5. Hansen, J-P. and Hayter, J.B., Mol. Phys. 46, 651 (1982).Google Scholar
6. Hayter, J.B., In ORNL Report No. ORNL-6306, 1986, pp. 153–154. Computer programs to evaluate S(Q) and g(r) for charge-stabilized dispersions are available from the author.Google Scholar
7. Hayter, J.B. and Snook, I.K. (to be published).Google Scholar
8. Hayter, J.B. and Penfold, J., Coll. Polym. Sci., 261, 1022 (1983).Google Scholar
9. Goodwin, J.W., Ottewill, R.H., Owens, S.M., Richardson, R.A. and Hayter, J.B., Makromol. Chem., Suppl. 10/11, 499 (1985).CrossRefGoogle Scholar
10. Williams, R. and Crandall, R.S., Phys. Lett. A 48, 225 (1974).Google Scholar
11. Ackerson, B.J., Hayter, J.B., Clark, N.A. and Cotter, L., J. Chem. Phys., 84, 2344 (1986).Google Scholar
12. Ackerson, B.J. and Clark, N.A., Phys. Rev. A 30, 906 (1984).Google Scholar
13. Wignall, G.D., in Encyclopedia of Polymer Science and Engineering, 2nd ed., edited by M. Grayson and J.I. Kroschwitz (Wiley, New York, in press).Google Scholar
14. Moon, R.M., Riste, T. and Koehler, W. C., Phys. Rev. 189, 920 (1969).CrossRefGoogle Scholar