Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-09T05:40:32.875Z Has data issue: false hasContentIssue false

NDE Observations of Hydrogen Effects in 4340 Steel

Published online by Cambridge University Press:  21 February 2011

In-Ok Shim
Affiliation:
Department of Metallurgy and Metallurgical Engineering, University of Utah, Salt Lake City, Utah 84112-1183, U.S.A.
J. G. Byrne
Affiliation:
Department of Metallurgy and Metallurgical Engineering, University of Utah, Salt Lake City, Utah 84112-1183, U.S.A.
Get access

Abstract

Cathodic charging of hydrogen into 4340 steel produces drastic deterioration of mechanical properties such as the notch tensile strength, depending on current density, charging time, and the poison used as an inhibitor of hydrogen recombination and bubble formation at the specimen surface. Fusion of charged samples permitted hydrogen content to be measured and revealed a linear increase in the latter with charging current density. The change in the Doppler spectrum sharpness parameter Δ(P/W) deviates negatively with cathodic charging time but inversely with the charging current density (fugacity). Thus a low-fugacity hydrogen charging appears merely to screen existing positron trap sites, whereas a high-fugacity charge also creates new defect traps. This would result in a lesser net screeninig effect which would be seen as a smaller negative deviation in Δ(P/W) as observed. For cumulative charging, however, one finds oscillatory behavior in (P/W) as in earlier cumulative charging experiments with Ni. This behavior indicates that hydrogen screening of positron traps was followed by new positron trap site creation and that this sequence of events occurred repeatedly and in that order.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. West, R. N., Adv. Phys. 22, 405 (1973).Google Scholar
2. Stewart, A. T., in Positron Annihilation, edited by Stewart, A. T. and Roellig, L. O. (Academic Press, New York, 1967), p. 17.CrossRefGoogle Scholar
3. Seeger, A., in Frontiers in Materials Science, edited by Murr, L. E. and Stein, C. (Marcel Dekker Inc., 1976), p. 177.Google Scholar
4. West, R. N., in Positrons in Solids, Topics in Current Physics, vol.12, edited by Hautojarvi, P. (Springer-Verlag, Berlin, 1979), p. 89.Google Scholar
5. Byrne, J. G., in Dislocations in Solids, edited by Nabarro, F. R. N. (North-Holland Pub. Co., 1981), p. 263.Google Scholar
6. Seeger, A., Appl. Phy. 4, 183 (1974).Google Scholar
7. Nieminen, R. M. and Manninen, M. J., in Positrons in Solids, Topics in Current Physics, vol.12, edited by Hautojarvi, P. (Springer-Verlag, Berlin, 1979). p. 145.CrossRefGoogle Scholar
8. Alex, F., Hadnagy, T. O., Lynn, K. G. and Byrne, J. G., AIME Conference on Effect of Hydrogen on Behavior of Materials (1975), 642.Google Scholar
9. Kao, P. W., Ure, R. W., and Byrne, J. G., Phil. Mag. 39A, 514 (1979).Google Scholar
10. Byrne, J. G. and Alex, F., U.S. Patent No. 4,064,438 (Dec. 1977).Google Scholar
11. Panchanadeeswaran, S. and Byrne, J. G., Scripta Met., 17, 1329 (1983).Google Scholar
12. Kim, J. J. and Byrne, J. G., Scripta Met., 17, 773 (1983).Google Scholar
13. Pan, Yi and Byrne, J. G., Materials Science and Engineering, 74, 215 (1985).CrossRefGoogle Scholar
14. Pan, Yi and Byrne, J. G., Materials Science and Engineering, 814, 195 (1986).CrossRefGoogle Scholar
15. Harvey, I. R. and Byrne, J. G., Review of Progress in Quantitative NDE, presented at Review of Progress in Quantitative NDE, U.C. San Diego, Aug. 1–5, 1988 (in press).Google Scholar
16. Johnson, M. L., Saterlie, S. and Byrne, J. G., Met. -Trans. 9A, 841 (1978).CrossRefGoogle Scholar
17. Shim, In-Ok, Ph.D. Thesis, University of Utah, 1988.Google Scholar
18. Oriani, R. A., in Fundamentals of Stress Corrosion Cracking, edited by Staehl, R. W., Hochmann, J., McCright, R. D., and Slater, J. E. (NACE-5, NACE, 1977), 225.Google Scholar
19. Lacombe, P., Aucouturier, M., and Chene, J., in Hydrogen Embrittlement and Stress Corrosion Cracking, edited by Gibala, R. and Heheman, R. F. (ASM, Cleveland, 1984), 79.Google Scholar
20. Asaoka, T., in Metal-Hydrogen Systems (Pergamon Press, Oxford, 1982), 197.Google Scholar