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The Nature of Fluorine Modified Oxide Surfaces: An Nmr Study

Published online by Cambridge University Press:  15 February 2011

John R. SCHLUP  and
Robert W. Vaughan
John R. SCHLUP
Affiliation:
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125
Robert W. Vaughan
Affiliation:
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125
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Abstract

Fluorine modified oxide surfaces have received considerable attention both as research materials and as commercial catalysts. Pulsed NMR has been used to directly observe protons and fluorine on fluorine modified silica,alumina, and aluminosilicates. The center of mass of the 19F spectra is consistent with values reported for covalent siliconfluorine and aluminum-fluorine bonds. The proton and fluorine concentrations have been investigated as a function of sample preparation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 3: Symposium – Nuclear and Electron Resonance Spectroscopies Applied to Materials Science , 1980 , 265
Copyright
Copyright © Materials Research Society 1981

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References

REFERENCES

1. Choudhary, V. R., Ind. Eng. Chem., Prod. Res. Dev. 16, 12 (1977).Google Scholar
2. Sidorov, A. N. and Neimark, I. E., Russ. J. Phys. Chem. 38, 1518 (1964).Google Scholar
3. Vaughan, R. W., Elleman, D. D., Stacey, L. M., Rhim, W.–K., and Lee, J. W., Rev. Sci. Instrum. 43, 1356 (1972).Google Scholar
4. Schreiber, L. B. and Vaughan, R. W., J. Catal. 40, 226 (1975).Google Scholar