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Nature of Charged Metastable Defects in Network Rebonding Model

Published online by Cambridge University Press:  01 February 2011

R. Biswas
Affiliation:
Department of Physics and Astronomy, Microelectronics Research Center and Ames Laboratory-USDOE, Iowa State University, Ames, Iowa 50011
B. C. Pan
Affiliation:
Department of Physics and Astronomy, Microelectronics Research Center and Ames Laboratory-USDOE, Iowa State University, Ames, Iowa 50011 Department of Physics, University of Science and Technology of China, Hefei 230026, People's Republic of China
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Abstract

We recently developed an atomistic model of metastability of a-Si:H, where defect creation is driven by the breaking of weak silicon bonds. The kinetics of degradation in this model is simulated with coupled rate equations that show t1/3 kinetics of defect creation and saturation behavior similar to experiment. Saturated defect densities of neutral dangling bonds are accompanied by a much smaller density of negatively charged floating bonds and positively charged dangling bonds (D+). We propose a two-step annealing mechanism where the positively charged D+ dangling bonds are annealed at low temperature and the D0 at higher temperature -which accounts for hysteresis in mobility lifetime products.

Type
Research Article
Copyright
Copyright © Materials Research Society 2002

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References

[1] Staebler, D. L., and Wronski, C. R., Appl. Phys. Lett. 31, 292 (1977).Google Scholar
[2] Stutzmann, M., Jackson, W. and Tsai, C. C., Phys. Rev. B 32, 23 (1985).Google Scholar
[3] Wronski, C. MRS 467, 7 (1997).Google Scholar
[4] Pearce, J., Niu, X., Koval, R., Ganguly, G., Carlsson, D., Collins, R.W. and Wronski, C.R., MRS 664, A 12 (2001).10.1557/PROC-664-A12.3Google Scholar
[5] Han, D. and Fritzsche, H., J. Non. Cryst. Solids 59-60, 397 (1983).Google Scholar
[6] Stradins, P., Shimizu, S., Kondo, M., Matsuda, A., MRS 664, A12 (2001).Google Scholar
[7] Heck, S. and Branz, H., MRS 664, A 12.2 (2001).Google Scholar
[8] Biswas, R., Pan, B.C. and Ye, Y., preprint and J. Non. Cryst. Solids (2002).Google Scholar
[9] Zhang, S.B. and Branz, H., Phys. Rev. Lett. 84, 967 (2000).Google Scholar
[10] Pantelides, S., Phys. Rev. Lett. 58, 1344 (1987); Phys. Rev. B 36, 3479 (1987).Google Scholar
[11] Branz, H., Solid State Comm. 105, 387 (1998); Phys. Rev. B 59, 5498 (1999).Google Scholar
[12] Parameters used include Nw=2e19cm-3,NH= 5e21cm-3,kw=5e-21s,kr=kf= 8e-21 cm3s-1,C1=1e-23cm3s-1, D0=5e-24cm3s-1. Results are insensitive to small changes in parameters.Google Scholar
[13] Shimizu, T. and Kumeda, M., Jpn. J. Appl. Phys. 38, l911 (1998).Google Scholar
[14] McMahon, T. and Crandall, R., Phys. Rev. B 39, 1766 (1982).Google Scholar