Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-17T17:10:56.915Z Has data issue: false hasContentIssue false
  • English
  • Français

NASICON-like phases in ScPO4-Na3PO4-Li3PO4 quasiternary system

Published online by Cambridge University Press:  01 February 2011

Mariya Zhuravleva ,
Ruslan Zakalyukin ,
Valeriy Fomichev ,
Andrey Novoselov ,
Akira Yoshikawa ,
Tsuguo Fukuda  and
Galina Zimina
Mariya Zhuravleva
Affiliation:
[email protected], Lomonosov Moscow State Academy of Fine Chemical Technology, Vernadskogo Av. 86, Moscow, N/A, 119571, Russian Federation
Ruslan Zakalyukin
Affiliation:
[email protected], Lomonosov Moscow State Academy of Fine Chemical Technology, Vernadskogo Av. 86, Moscow, N/A, 119571, Russian Federation
Valeriy Fomichev
Affiliation:
[email protected], Lomonosov Moscow State Academy of Fine Chemical Technology, Vernadskogo Av. 86, Moscow, N/A, 119571, Russian Federation
Andrey Novoselov
Affiliation:
[email protected], Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Division of Advanced Crystal Materials, Katahira 2-1-1, Aoba-ku, Sendai, N/A, 980-8577, Japan
Akira Yoshikawa
Affiliation:
[email protected], Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Division of Advanced Crystal Materials, Katahira 2-1-1, Aoba-ku, Sendai, N/A, 980-8577, Japan
Tsuguo Fukuda
Affiliation:
[email protected], Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Division of Advanced Crystal Materials, Katahira 2-1-1, Aoba-ku, Sendai, N/A, 980-8577, Japan
Galina Zimina
Affiliation:
[email protected], Lomonosov Moscow State Academy of Fine Chemical Technology, Vernadskogo Av. 86, Moscow, N/A, 119571, Russian Federation
Get access

Abstract

Phase formation in ternary system of complex Sc, Na and Li phosphates was studied at 950°C and synthesis of new phases of definite composition was carried out. Obtained samples were investigated with X-ray powder diffraction, infrared and impedance spectroscopy. Compositions of fields of homogeneity with the NASICON-like structure were discovered. Temperature dependency of ionic conductivity was measured.

Keywords

ceramicionic conductorphase equilibria
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 936: Symposium L – Materials for Next-Generation Display Systems , 2006 , 0936-L01-06
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Hong, H.Y.P., Mat. Res. Bull. 11 173 (1976).Google Scholar
2 Goodenough, J.B., Hong, H.Y.P., and Cafalas, J.A., Mat. Res. Bull. 11 203 (1976).Google Scholar
3 Collongues, R., Kahn, A., and Michel, D., Ann. Rev. Mater. Res. 9 123 (1979).Google Scholar
4 Kohler, H. and Schulz, H., Solid State Ionics. 9–10 795 (1983).Google Scholar
5 Boilot, J.P., Collin, G., and Comes, R., Solid State Ionics 9–10 829 (1983).Google Scholar
6 Feltz, A. and Barth, S., Solid State Ionics 9–10 817 (1983).Google Scholar
7 Kalinin, V.B., Ph.D. Thesis, Moscow State University, Russia, 1975.Google Scholar
8 Efremov, V.A. and Kalinin, V.B., Crystallogr. Reports 23 393 (1978).Google Scholar
9 Susman, S., Delbecq, C.J., and Brun, T.O., Solid State Ionics 9–10 839 (1983).Google Scholar
10 Kalinin, V.B., Lazoryak, B.I., and Stefanovich, S. Yu., Crystallogr. Reports 28 154 (1983).Google Scholar
11 Sigaryov, S.E., Solid State Commun. 75 1005 (1990).Google Scholar
12 d'Yvoire, F., Pintard-Screpel, M., Bretey, E., and Rochere, M. de la, Solid State Ionics 9–10 851 (1983).Google Scholar
13 Genkina, E.A., Muradyan, L.A., Maksimov, B.A., Merinov, B.V., and Sigarev, S.E., Crystallogr. Reports 32 40 (1987).Google Scholar