Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-29T07:24:00.305Z Has data issue: false hasContentIssue false
  • English
  • Français

Nanoscale Surface Modification of UltraHigh Molecular Weight Polyethylene (UHMWPE) Samples with the W + C Ion Implantation

Published online by Cambridge University Press:  01 February 2011

E. Sokullu Urkac ,
A. Oztarhan ,
F. Tihminlioglu ,
N. Kaya ,
S. Budak ,
B. Chhay ,
C. Muntele ,
E. OKs ,
A. Nikolaev  and
D. ILA
E. Sokullu Urkac
Affiliation:
[email protected], Ege University, Department of Bioengineering, Bornova, 35100, Turkey
A. Oztarhan
Affiliation:
[email protected], Ege University, Department of Bioengineering, Bornova, 35100, Turkey
F. Tihminlioglu
Affiliation:
[email protected], IYTE, Department of Chemical Engineering, Urla, 35000, Turkey
N. Kaya
Affiliation:
[email protected], Ege University, Department of Bioengineering, Bornova, 35100, Turkey
S. Budak
Affiliation:
[email protected], Alabama A&M University, Center for Irradiation of Materials, 4900 Meridian Street, PO Box 1447, Huntsville, AL, 35762, United States
B. Chhay
Affiliation:
[email protected], Alabama A&M University, Center for Irradiation of Materials, 4900 Meridian Street, PO Box 1447, Huntsville, AL, 35762, United States
C. Muntele
Affiliation:
[email protected], Alabama A&M University, Center for Irradiation of Materials, 4900 Meridian Street, PO Box 1447, Huntsville, AL, 35762, United States
E. OKs
Affiliation:
[email protected], High Current Electronics Institute, Tomsk, 44000, Russian Federation
A. Nikolaev
Affiliation:
[email protected], High Current Electronics Institute, Tomsk, 44000, Russian Federation
D. ILA
Affiliation:
[email protected], Alabama A&M University, Center for Irradiation of Materials, 4900 Meridian Street, PO Box 1447, Huntsville, AL, 35762, United States
Get access

Abstract

In this work, Ultra High Molecular Weight Poly Ethylene (UHMWPE) samples were implanted with W + C ion by using Metal-Vapour Vacuum Arc (MEVVA) ion implantation technique. Samples were implanted with W and C atoms with a fluence of 1017ion/cm2 and extraction voltage of 30 kV. Mechanism underlies this modification characterized with ATR-FTIR, UV-VIS-NIR Spectrum and Rutherford Backscattering Spectrometry (RBS). Surface morphology of implanted and unimplanted samples were examined in nanoscale with AFM.

Keywords

nanoscaleion-implantationpolymerization
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1020: Symposium GG – Ion-Beam-Based Nanofabrication , 2007 , 1020-GG07-05
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Black, J., Hastings, G., Handbook of Biomaterial Properties, 1998, Chapman & Hall.Google Scholar
2. Doerner, R.P., Journal of Nuclear Materials, 363–365, 32–40, 2007.Google Scholar
3. Doolittle, L.R., “Algorithms for the rapid simulation of Rutherford backscattering spectra”, Nucl. Instr. and Meth. B, 9,344, 1985.Google Scholar
4. Turos, A., Abdul-Kader, A.M., Grambole, D., Jagielski, J., Piatkowska, A., Madi, N.K. and Al-Maadeed, M., “The effects of ion bombardment of ultra-high molecular weight polyethylene”, Nucl. Instr. and Meth. B, 249, 660–664, 2006.Google Scholar
5. Rizzatti, M.R., Araújo, M.A. and Livi, R.P., “The fluence effect of Ar++ bombardment in PPS”, Nucl. Instr. and Meth. B, 174, 475–481, 2001.Google Scholar
6. Braun, M., “Ion bombardment as a tool to modify surface properties of different materials”, Vacuum, 38, 973–977, 1988.Google Scholar
7. Evelyn, A.L., Ila, D., Zimmerman, R.L., Bhat, K., Poker, D.B. and Hensley, D.K., “Effects of MeV ions on PE and PVDC”, Nucl. Instr. and Meth. B, 141, 164–168, 1998.Google Scholar
8. Davenas, J. and Xu, X.L.., “Relation between structure and electronic properties of ion irradiated polymers”, Nucl. Instr. and Meth. B, 39, 754, 1989.Google Scholar
9. Premnath, V., Bellare, A., Merrill, E. W., Jasty, M. and Harris, W. H., “Molecular rearrangements in ultra high molecular weight polyethylene after irradiation and long-term storage in air”, Polymer, 40, 2215–2229, 1999.Google Scholar
10. Bracco, P., Prever, del Brach, E.M., Cannas, M., Luda, M.D. and Costa, L., “Oxidation behaviour in prosthetic UHMWPE components sterilised with high energy radiation in a low-oxygen environment”, Polymer Degradation and Stability, 91, 2030–2038, 2006.Google Scholar
11. Urkac, E. Sokullu, Oztarhan, A., Tihminlioglu, F., Kaya, N., Ila, D., Muntele, C., Budak, S., Oks, E., Nikolaev, A., Ezdesir, A., Tek, Z., “Thermal Characterization of Ag and Ag+N ion implantated Ultra High Molecular Weight Polyethylene (UHMWPE)”, Nucl. Instr. and Meth. B, 2007, In Press.Google Scholar
12. Kaya, N., Oztarhan, A., Urkac, E. Sokullu, Ila, D., Budak, S., Oks, E., Nikolaev, A., Ezdesir, A., Tihminlioglu, F., Tek, Z., “Polymeric Thermal Analysis of C+H and C+H+Ar Ion Implanted UHMWPE Samples”, Nucl. Instr. and Meth. B, 2007, In Press.Google Scholar
13. Kostov, K. G., Ueda, M., Tan, I. H., Leite, N.F., Beloto, A.F. and Gomes, G.F., “Structural effect of nitrogen plasma-based ion implantation on ultra-high molecular weight polyethylene”, Surface and Coatings Technology, 186, 287–290, 2004.Google Scholar
14. Chen, J., Zhu, F., Pan, H., Cao, J., Zhu, D., Xu, H., Cai, Q., Shen, J., Chen, L. and He, Z., “Surface modification of ion implanted ultra high molecular weight polyethylene”, Nucl. Instr. and Methods B, 169, 26–30, 2000.Google Scholar
15. Lewis, G., “Properties of crosslinked ultra-high-molecular-weight polyethylene”, Biomaterials, Vol 22, Issue 4, pp 371–401, 2001.Google Scholar
16. Gispert, M. P., Serro, A.P., Colaço, R. and Saramago, B., “Friction and wear mechanisms in hip prosthesis: Comparison of joint materials behaviour in several lubricants”, Wear, Vol 260, Issues 1-2, pp. 149–158, 2006.Google Scholar