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Nanocrystalline gold and gold-palladium as effective catalysts for selective oxidation

Published online by Cambridge University Press:  01 February 2011

Jennifer Edwards ,
Philip Landon ,
Albert F. Carley ,
Andrew Herzing ,
Masashi Watanabe ,
Christopher J. Kiely  and
Graham Hutchings
Jennifer Edwards
Affiliation:
Department of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK
Philip Landon
Affiliation:
Department of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK
Albert F. Carley
Affiliation:
Department of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT, UK
Andrew Herzing
Affiliation:
Center for Advanced Materials and Nanotechnology, Lehigh University, 5 East Packer Avenue, Bethlehem, PA 18015-3195, USA.
Masashi Watanabe
Affiliation:
Center for Advanced Materials and Nanotechnology, Lehigh University, 5 East Packer Avenue, Bethlehem, PA 18015-3195, USA.
Christopher J. Kiely
Affiliation:
Center for Advanced Materials and Nanotechnology, Lehigh University, 5 East Packer Avenue, Bethlehem, PA 18015-3195, USA.
Graham Hutchings
Affiliation:
[email protected], Cardiff University, Chemistry, Park Place, Cardiff, N/A, N/A, United Kingdom
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Abstract

The recent interest in oxidation catalysis provides the focus for this paper. Until recently gold has been overlooked as a key component of both homogeneous and heterogeneous catalysts. However, the observation in the 1980's that nanocrystalline gold supported on oxides was an effective catalyst for low temperature carbon monoxide oxidation has now captured the imagination of many researchers. At present low temperature carbon monoxide oxidation remains an intensely studied field, but in recent years increased emphasis has been placed on using gold catalysts for selective oxidation. For example the oxidation of alkanes, alkenes and alcohols have all been shown to be effective with gold based catalysts. In addition gold palladium catalysts have been shown to be very effective for the direct formation of hydrogen peroxide and this will be described in this paper.

Keywords

Aucatalyticalloy
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 900: Symposium O – Nanoparticles and Nanostructures in Sensors and Catalysis , 2005 , 0900-O01-07
Copyright
Copyright © Materials Research Society 2006

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