Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-23T07:42:32.785Z Has data issue: false hasContentIssue false

Modeling a Cement Degradation Experiment by a Hydraulic Transport and Chemical Equilibrium Coupled Code

Published online by Cambridge University Press:  10 February 2011

W. Pfingsten
Affiliation:
Paul Scherrer Institute, 5232 Villigen-PSI, Switzerland, [email protected]
M. Shiotsuki
Affiliation:
PNC, Akasaka Minato-ku, Tokyo, Japan, [email protected]
Get access

Abstract

An experiment degrading a porous cement disc by pure water was modelled by a reactive transport model including chemical reactions, mineral precipitation/dissolution reactions and changing hydraulic properties of the cement. For the early cement degradation or high pH phase, an equilibrium sorption approach is used for the release of alkali metals. Porosity changes of the porous cement disc during degradation induce conductivity changes that are taken into account in the modelling by coupling back transport to geochemical parameters.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Atkins, A. and Glasser, F.P., Application of Portland Cement -Based Materials to Radioactive Waste Immobilization. Waste Management, 1992. 12: p. 105131.Google Scholar
2 Lee, J.H. and Roy, D.M., Modeling of Alkali Ion Leaching from the Concrete Pad Barrier into the Underlying Saturated Soil in Above-Grade Tumulus LLRW Disposal Facility. J. of American Ceramic Society, 1994.:p. 287297.Google Scholar
3 Atkins, A. and Glasser., F.P. The long-term properties of cement and concretes. in Mat. Res. Soc. Symp. 1991. Materials Research Society.Google Scholar
4 Neall, F. Modeling of the near-field chemistry of the SMA repository at the Wellenberg site. Paul Scherrer Institut, PSI-Bericht 94–18 (1994)Google Scholar
5 Sarott, F.A. et al. , Diffusion and adsorption studies on hardened cement paste and the effect of carbonation on diffusion rates. Cement and Concrete Research, 1992. 22: p. 439444.Google Scholar
6 Dewaele, P.J., Reardon, E.J., and Dayal, R., Permeability and Porosity Changes Associated with Cement Grout Carbonation. Cement and Concrete Research, 1991. 21: p. 441454.Google Scholar
7 Gerard, B. et al. Modelling the Long-Term Durability of Concrete for Radioactive Waste Disposals. in MRS Symp. Mechanisms of Chemical Degradation of Cement-based Systems. 1996. Boston, USA: E&FN Spoon, London, UK.Google Scholar
8 Lichtner, P.C. and Eikenberg, J.. Propagation of a Hyperalkaline Plume into a Geological Barrier Surrounding a Radioactive Waste Repository. PSI, PSI-Report 95–01 (1995)Google Scholar
9 Berner, U.R., Evolution of Pore Water Chemistry During Degradation of Cement in a Radioactive Waste Repository Environment. Waste Management, 1992. 12: p. 201219.Google Scholar
10 Pfingsten, W., Efficient Modeling of Reactive Transport Phenomena by a Multispecies Random Walk Coupled to Chemical Equilibrium. Nuclear Technology, 1996. 116(2): p. 208221.Google Scholar
11 Houst, Y.F. Microstructural changes of hydrated cement Paste due to carbonisation. in MRS Symp. Mechanisms of Chemical Degradation of Cement-based Systems. 1996. Boston, USA: E&FN Spoon, London, UK.Google Scholar
12 Shiotsuki, M. and Pfingsten, W.. Application of a coupled code to a cement degradation experiment (PSI Report, in prep.). Paul Scherrer Institut, (1997)Google Scholar
13 Pfingsten, W. Modular Coupling of Transport and Chemistry: Theory and Model Applications. Paul Scherrer Institut, PSI-Bericht 94–15 (1994)Google Scholar
14 Bear, J., Dynamics of Fluids in Porous Media. 1988, Dover Publications Inc.Google Scholar
15 Oelkers, E.H. Physical and Chemical Properties of Rocks and Fluids for Chemical Mass Transport Calculations. in Reactive Transport in Porous Media. 1996. Mineralogical Society of America, Washington, DC.Google Scholar
16 Bakharev, T. et al. Durability of Cement Stabilised Low Level Wastes. in MRS Symp. Mechanisms of Chemical Degradation of Cement-based Systems. 1996. Boston, USA: E&FN Spoon, London, UK.Google Scholar
17 Taylor, H.F.W., A method for predicting alkali ion concentrations in cement pore solutions. Advances in Cement Research, 1987. 1(1): p. 516.Google Scholar
18 Berner, U.R., Modelling the Incongruent Dissolution of Hydrated Cement Minerals. Radiochimica Acta, 1988. 44/45: p. 387393.Google Scholar