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Published online by Cambridge University Press: 21 February 2011
In this work, we develop a model for ion-assisted molecular beam epitaxy with application to synthesis of epitaxial SnxGe1-x/Ge/Si(001) with compositions up to x=0.34. The model describes the effect of energetic beam deposition on surface segregation during thin film growth. As the value of a Péclet number expressing the ratio of surface ion-mixing rate to growth rate exceeds unity, the segregation coefficient during ion-assisted growth exceeds the value during thermal growth. A comparison of the model with experiments for SnxGei.1-x synthesis is reported. The experimental results are consistent with the model.