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Microstructure and Phase Characterization of the Surface of a-C:H Films by Means of Scanning Tunneling Microscopy and Spectroscopy
Published online by Cambridge University Press: 10 February 2011
Abstract
Scanning Tunneling Microscopy and Spectroscopy (STM/STS) are used for obtaining nano-scale information on morphological and electronic properties of the surface of diamond-like amorphous hydrogenated carbon (a-C:H) filns. The films are prepared by rf plasma decomposition of methane CH4.A two phase model of a-C:H is suggested - sp3 bonded matrix in which sp2 clusters are embedded. A novel method of mapping graphite-like clusters over a-C:H surface is proposed. Tunneling I/V characteristics with a gap acquired on indium tin oxide (ITO) deposited on a-C:H indicate location of sp2 regions at the surface of a-C:H below an ITO overlayer
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- Copyright © Materials Research Society 1996