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Microstructure and Fracture At the Cement Paste-Aggregate Interface

Published online by Cambridge University Press:  21 February 2011

L. Struble*
Affiliation:
Center for Building Technology, National Bureau of Standards, Gaithersburg, MD 20899.
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Abstract

The mechanical behavior of concrete is thought to be affected by the microstructure of the paste-aggregate interface, which differs in several respects from the microstructure of bulk paste. General aspects of interfacial microstructure, which appear to be fairly well understood, are reviewed. Recent microstructural studies using backscattered electron imaging show that there is a zone along the interface (approximately 50 μm wide) within which there are generally few large unhydrated clinker grains, many large voids (greater than 5 μm), a generally porous microstructure, many hollow-shell hydration grains, and in some cases little calcium hydroxide. The tendency for cracks to develop or grow along the paste-aggregate interface is discussed in relation to specific features of the interfacial microstructure.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

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References

REFERENCES

1. Diamond, S., in Proceedings of the Eighth International Congress on the Chemistry of Cement, I, (General Secretariat, Rio, 1986) pp. 122147.Google Scholar
2. Grandet, J. and Ollivier, J., in Seventh International Congress on the Chemistry of Cement, III, (Editions Septima, Paris, 1980) pp. VII63.Google Scholar
3. Monteiro, P.J.M., PhD thesis, University of California, Berkeley, 1985.Google Scholar
4. Yuan, C.Z. and Odler, I., Cem. Concr. Res. 17, 784 (1987).Google Scholar
5. Diamond, S., presented at the 66th Annual Meeting of the Transportation Research Board, Washington DC, 1987 (unpublished).Google Scholar
6. Diamond, S., in Microstructural Development During Hydration of Cement, edited by Struble, L.J. and Brown, P.W., (Mater. Res. Soc. Proc. 85, Pittsburgh, PA, 1987) pp. 2131.Google Scholar
7. Scrivener, K.L. and Pratt, P.L., in Proceedings of the Eighth International Congress on the Chemistry of Cement, III, (General Secretariat, Rio, 1986) pp. 466471.Google Scholar
8. Ringot, E., Ollivier, J.P., and Maso, J.C., Cem. Concr. Res. 17, 411 (1987).Google Scholar
9. Kayyali, O.A., Mater. Constr. (Paris) 20, 19 (1987).Google Scholar
10. Monteiro, P.J.M. and Mehta, P.K., in Proceedings of the Eighth International Congress on the Chemistry of Cement III, (General Secretariat, Rio, 1986) pp. 433437.Google Scholar
11. Zimbelmann, R., Cem. Concr. Res. 15, 801 (1985).Google Scholar
12. Yuan, C.Z. and Guo, W.J., Cem. Concr. Res. 17, 544 (1987).Google Scholar
13. Yuan, C.Z. and Zhong, Z.X., in Proceedings of the Eighth International Congress on the Chemistry of Cement, III, (General Secretariat, Rio, 1986) pp. 449453.Google Scholar
14. Khalaf, M.N. Al and Page, C.L., Cem. Concr. Res. 9, 197 (1979).Google Scholar
15. Zimbelmann, R., Cem. Concr. Res. 17, 651 (1987).CrossRefGoogle Scholar
16. Conjeaud, M., Lelong, B., and Cariou, B., in Proceedings of the Seventh International Congress on the Chemistry of Cement III, (Editions Septima, Paris, 1980) pp. VII6 Google Scholar
17. Berger, R.L., Cahn, D.S., and McGregor, J.D., J. Am. Ceram. Soc. 53, 57 (1970).CrossRefGoogle Scholar
18. Hsu, T.T.C., Slate, F.O., Sturman, G.M., and Winter, G., J. Amer. Concr. Inst. 60, 209 (1963).Google Scholar
19. Hornain, H. and Regourd, M., in Proceedings of the Eighth International Congress on the Chemistry of Cement, V, (General Secretariat, Rio, 1986) pp. 5359.Google Scholar
20. Maji, A.K. and Shah, S.P., Report for the Center for Concrete and Geomaterials, Northwestern University, 1987.Google Scholar
21. Saito, M. and Kawamura, M., Cem. Concr. Res. 16, 653 (1986).Google Scholar
22. Giaccio, G. and Zerbino, R., in Proceedings of the Eighth International Congress on the Chemistry of Cement, VI, (General Secretariat, Rio, 1986) pp. 331333.Google Scholar
23. Bentur, A., Diamond, S., and Mindess, S., J. Mater. Sci. 20, 3610 (1985).Google Scholar
24. Hillemeier, B. and Hilsdorf, H.K., Cem. Concr. Res. 7, 523 (1977).Google Scholar
25. Barker, A.P., Barnes, P., Fisher, G.R., and Jennings, H., in Proceedings of the Sixth International Conference on Cement Microscopy, (ICMA, Duncanville, 1984) pp. 5–19.Google Scholar
26. Barker, A.P. and Barnes, P., in Proceedings of the Sixth International Conference on Cement Microscopy, (ICMA, Duncanville, 1984) pp. 156–172.Google Scholar
27. Scrivener, K.L. and Pratt, P.L., in Proceedings of the Sixth International Conference on Cement Microscopy, (ICMA, Duncanville, 1984) pp. 145–155.Google Scholar
28. Struble, L. and Byrd, E., NBS Report NBSIR 87–3504, 1987.Google Scholar
29. Struble, L. and Stutzman, P., NBS Report NBSIR 88–3702, 1988.Google Scholar
30. Pielert, J.H., Haverfield, J.W., and Spellerberg, P.A., Cem. Concr. Agg. 2, 37 (1985).Google Scholar
31. Struble, L., PhD thesis, Purdue University, 1987.Google Scholar
32. Struble, L. and Mindess, S., Int. J. Cem. Compos. Lightweight Concr. 5, 79 (1983).CrossRefGoogle Scholar
33. Clifton, J.R., NBS Report NBSIR 87–3542, 1987.Google Scholar
34. Beaudoin, J.J., Cem. Concr. Res. 13, 319 (1983).Google Scholar
35. Tabor, D., in Adhesion Problems in the Recycling of Concrete, edited by Kreijger, P.C. (Plenum Press, London, 1981) pp. 6390.Google Scholar
36. Baldie, K. and Pratt, P., presented at the 86th Annual Meeting of the American Ceramic Society, Pittsburgh, PA, 1984 (unpublished).Google Scholar
37. Mai, Y.-W. and Cotterell, B., Cem. Concr. Res. 15, 995 (1985).CrossRefGoogle Scholar
38. Jennings, H.M., Struble, L.J., Clifton, J.R., and Frohnsdorff, G., in Proceedings. First NCB International Seminar on Pragmatic Strategies for Productivity and Modernisation, 4, (National Council for Cement and Building Materials, New Delhi, 1987) pp. IX–l.Google Scholar