Hostname: page-component-cd9895bd7-7cvxr Total loading time: 0 Render date: 2024-12-27T01:46:38.839Z Has data issue: false hasContentIssue false

Microstructural Behavior of Energetic Crystalline Aggregates

Published online by Cambridge University Press:  10 April 2013

D. LABARBERA
Affiliation:
Dept. of Mechanical and Aerospace Engineering, North Carolina State University, Raleigh, NC 27695-7910
M.A. ZIKRY
Affiliation:
Dept. of Mechanical and Aerospace Engineering, North Carolina State University, Raleigh, NC 27695-7910
Get access

Abstract

A dislocation-density based crystalline plasticity and specialized finite-element formulations were used to study the behavior of energetic crystalline aggregates. The energetic crystalline material studied was RDX (cyclotrimethylene trinitramine) with a polymer binder and different void porosities. The aggregate was subjected to different dynamic pressures, and the analyses indicate that maximum temperature increases, constrained dislocation densities, and plastic strain accumulations occurred around the void peripheries, which affected overall deformation behavior. These regions of extreme temperature rise and thermal decomposition can result in hot spot formation.

Type
Articles
Copyright
Copyright © Materials Research Society 2013

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Czerski, H. and Proud, W.G., '“Relationship between the morphology of granular cyclotrimethylene-trinitramine and its shock sensitivity,” J.Appl.Phys., vol. 102, no. 11, 1 December 2007, pp. 113515.CrossRefGoogle Scholar
Borne, L., Mory, J. and Schlesser, F., '“Reduced Sensitivity RDX (RS-RDX) in Pressed Formulations: Respective Effects of Intra-Granular Pores, Extra-Granular Pores and Pore Sizes,” Propellants, Explosives, Pyrotechnics, vol. 33, no. 1, pp. 3743.CrossRefGoogle Scholar
Hooks, D.E., Ramos, K.J. and Martinez, A.R., '“Elastic-plastic shock wave profiles in oriented single crystals of cyclotrimethylene trinitramine (RDX) at 2.25 GPa,” J.Appl.Phys., vol. 100, no. 2, JUL 15, pp. 024908.CrossRefGoogle Scholar
Shanthraj, P. and Zikry, M.A., '“Dislocation-density mechanisms for void interactions in crystalline materials,” Int.J.Plast., vol. 34, no. 0, 7, pp. 154163. (a) (b)CrossRefGoogle Scholar
Ashmawi, W.M. and Zikry, M.A., '“Prediction of Grain-Boundary Interfacial Mechanisms in Polycrystalline Materials,” J.Eng.Mater.Technol., vol. 124, no. 1, January 2002, pp. 8896.CrossRefGoogle Scholar
Shvedov, K., '“Macrokinetics of decomposition of loose packed RDX in shock and detonation waves,” Russian Journal of Physical Chemistry, vol. 4, 2010, pp. 526.CrossRefGoogle Scholar
Williams, M. and Matei, M., '“The Decomposition of some RDX and HMX Based Materials in the One-Dimensional Time to Explosion Apparatus. Part 1. Time to Explosion and Apparent Activation Energy,” Propellants, Explosives, Pyrotechnics, vol. 31, no. 6, pp. 435441.CrossRefGoogle Scholar
Kameda, T. and Zikry, M.A., '“Three dimensional dislocation-based crystalline constitutive formulation for ordered intermetallics,” Scr.Mater., vol. 38, no. 4, 1/13, pp. 631636.CrossRefGoogle Scholar
Brown, E.N., Rae, P.J. and Orler, E.B., '“The influence of temperature and strain rate on the constitutive and damage responses of polychlorotrifluoroethylene (PCTFE, Kel-F 81),” Polymer, vol. 47, no. 21, 10/4, pp. 75067518.CrossRefGoogle Scholar
Armstrong, R.W. and Elban, W.L., '“Materials science and technology aspects of energetic (explosive) materials,” Materials Science and Technology, vol. 22, no. 4, pp. 381395.CrossRefGoogle Scholar
Gallagher, H.G., Halfpenny, P.J., Miller, J.C., Sherwood, J.N. and Tabor, D., '“Dislocation Slip Systems in Pentaerythritol Tetranitrate (PETN) and Cyclotrimethylene Trinitramine (RDX) [and Discussion],” Philosophical Transactions: Physical Sciences and Engineering, vol. 339, no. 1654, Energetic Materials, May 15, pp. pp. 293303.Google Scholar
Lee, W.M. and Zikry, M.A., '“High strain-rate modeling of the interfacial effects of dispersed particles in high strength aluminum alloys,” Int.J.Solids Structures, vol. 49, no. 23–24, 11/15, pp. 32913300.CrossRefGoogle Scholar