Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-27T02:39:37.155Z Has data issue: false hasContentIssue false
  • English
  • Français

Meso-scale Order Structure Prepared From Immiscible Polymer Blend Solutions

Published online by Cambridge University Press:  13 March 2014

Junhyeok Jang ,
Tsuyoshi Inoue ,
Masayuki Kawazoe  and
Hirohisa Yoshida
Junhyeok Jang
Affiliation:
Department of Applied Chemistry, Graduate School of Urban Environmental Science, Tokyo Metropolitan University, 1-1 Minami-Osawa Hachioji Tokyo 192-0397, Japan
Tsuyoshi Inoue
Affiliation:
Department of Applied Chemistry, Graduate School of Urban Environmental Science, Tokyo Metropolitan University, 1-1 Minami-Osawa Hachioji Tokyo 192-0397, Japan
Masayuki Kawazoe
Affiliation:
Research Center, Yokohama Rubber Co. Ltd. Oiwake, Hiratsuka, Kanagawa, Japan
Hirohisa Yoshida
Affiliation:
Department of Applied Chemistry, Graduate School of Urban Environmental Science, Tokyo Metropolitan University, 1-1 Minami-Osawa Hachioji Tokyo 192-0397, Japan
Get access

Abstract

The meso-scale hexagonally packed order structures were obtained by solvent casting from the immiscible polymer blend solutions. The order structures were the result of phase separation occurred at the evaporation front during the solvent casting, the so-called dissipative system. The order domains were flat spheres or ellipses on the matrix surface depending on the combination of polymer blends and solvent, the diameter of spheres were tunable from 0.5 to 3 μm by the casting condition, such as the solvent used for mixing and the evaporation rate. Three blend systems, NBR/SBR, NBR/BR and PMMA/BR, formed two dimensional order structures with the domain size in μm-scale by solvent casting from those homogeneous solutions. The conditions to obtain the two dimensional meso-scale order structure were evaluated.

Keywords

self-assemblyblendsolvent casting
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1663: Symposium WW – Self-Organization and Nanoscale Pattern Formation , 2014 , mrsf13-1663-ww03-60
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Lackowski, William M., Ghosh, Pradyut, and Crooks, Richard M.. J. Am. Chem. Soc., 121, 1419–1420 (1999)10.1021/ja983545qCrossRefGoogle Scholar
Béduer, A., Seichepine, F., Flahaut, E., Vieu, C.. Microelectronic Engineering, 97, 301–305 (2012)10.1016/j.mee.2012.04.011CrossRefGoogle Scholar
Yoshida, H., Netsu Sokutei, 31, 5 (2004)Google Scholar
Jung, S. Y., Yoshida, H., Colloids & Surfaces A, 284-285, 305-308 (2006)10.1016/j.colsurfa.2005.10.096CrossRefGoogle Scholar
Shimomura, M., “Supramolecular Polymers”, Edit by A. Ciferri, 471, Marcel Dekker, Inc., New York (2000)Google Scholar
Widawski, G., Rawiso, M., Franc, B.¸ois, Nature, 369, 387 (1994)10.1038/369387a0CrossRefGoogle Scholar
Maruyama, N., Koito, T., Nishida, J., Sawadaishi, T., Cieren, X., Ijiro, K., Karthaus, O., Shimomura, M., Thin Solid Films, 854, 327–329 (1998)Google Scholar
Wang, S.X., Wang, M.T., Lei, Y., Zhang, L.D., Mater. Res. Bull, 35, 1625 (2000)10.1016/S0025-5408(00)00359-7CrossRefGoogle Scholar
Cui, Liang, Peng, Juan, Ding, Yan, Li, Xue, Han, Yanchun polymer Journal 46, 5334–5340 (2005)10.1016/j.polymer.2005.04.018CrossRefGoogle Scholar
Jang, J.H., Yoshida, H., Kawazoe, M., Netsu Sokutei, W39, 33–39 (2012)Google Scholar
Hildebrand, J. H. and Scott, R. L., The Solubility of Non-Electrolytes, 3rd ed., Reinhold, New York (1959)Google Scholar
Scatchard, G., Chem. Rev., 8, 321 (1931)10.1021/cr60030a010CrossRefGoogle Scholar